Exploring cost-effective and durable
bifunctional oxygen electrocatalysts
for oxygen reduction and oxygen evolution reactions (ORR and OER)
is critical for the commercial implementation of rechargeable Zn–air
batteries but remains as an immense challenge. Herein, CoNi nanoalloys
wrapped with N-doped graphene embedded into N-doped carbon nanotubes
(CN@NC) have been prepared by a universal two-step pyrolysis method.
The optimal CN@NC–2–800 affords a positive half-wave
potential of 0.83 V for ORR and a small overpotential of 400 mV at
10 mA cm–2 for OER, outperforming most of the current
non-precious bifunctional oxygen electrocatalysts. Expectedly, the
liquid Zn–air battery based on CN@NC–2–800 displays
a high open-circuit voltage of 1.52 V, a large peak power density
of 172 mW cm–2, and a long cycle life of 300 h.
Furthermore, the developed all-solid-state Zn–air battery also
shows remarkable stability with various degrees of bending. This work
offers a simple and effective way to explore highly efficient and
durable electrocatalysts for renewable energy applications.
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