The hydroformylation of propene to linear-butaldehyde can be performed efficiently in a continuous fixed-bed reactor employing the copolymer self-supported heterogeneous Rh/CPOL-bp&P catalysts.

Photoswitchable fluorescent diarylethenes are promisingly widely applied in the fields of optical memory, all-optical transistors, bioimaging, and super-resolution imaging, and so on. However, they face the problems of fluorescence quenching in an aggregated/solid state, the inadequate fluorescence ON/OFF switching ratio, and the necessity of UV-light irradiation. Herein, we report a novel kind of high-performance diarylethenes with aggregated-induced emission (AIE) by conjugating two diarylethene groups on one AIE-gen (i.e., TPE-2DTE (blue-green fluorescent) and OTPE-2DTE (orange fluorescence)). Their open forms show enhanced fluorescence in the aggregated and solid states. The closed form of TPE-2DTE/OTPE-2DTE was effectively generated upon short-wavelength visible-light (400 nm-450 nm) irradiation, whose fluorescence was dramatically quenched by intra-and inter-molecular energy transfer. Remarkably, 405 nm purple irradiation gives fluorescence ON/OFF ratios of 1196:1 and 1983:1 for TPE-2DTE and OTPE-2DTE, respectively. The reverse process can be accomplished after another longer wavelength irradiation such as 621 nm and shows considerable fatigue resistance. Taking advantage of superior photoswitching properties under visible-light irradiation, TPE-2DTE and OTPE-2DTE were used for super-resolution imaging with a high resolution of sub 50 nm. This work offers guidance to design bright-emitting and highperformance visible-light-controlled diarylethene photoswitches for practical applications.

Understanding the interaction between nanoparticles (NPs) and cell membranes is crucial for the design of NP-based drug delivery systems and for the assessment of the risks exerted by the NPs. Recent experimental and theoretical studies have shown that cell membranes can mediate attraction between NPs and form tubular structures to wrap multiple NPs. However, the cooperative wrapping process is still not well understood, and the shape effect of NPs is not considered. In this article, we use largescale coarse-grained molecular dynamics (CGMD) simulations to study the cooperative wrapping of NPs when a varying number of NPs adhered to the membrane. Spherical, prolate and oblate NPs of different sizes are considered in this study. We find that, in addition to tubular structures, the membrane can form a pocket-like and a handle-like structure to wrap multiple NPs depending on the size and shape of the NPs. Furthermore, we find that NPs can mediate membrane hemifusion or fusion during this process.Our findings provide new insights into the interaction of NPs with the cell membrane.

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