The kinetic products derived from addition of phthalimide, /V-methyltoluenesulfonamide, or benzenethiol to homochiral Fp(dioxene)BF4 salts 2 and 3 [Fp = CpFe(CO)2] undergo unlmolecular dyotropic rearrangement, resulting in inversion of the two initially formed asymmetric centers.
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