Wearable sensors have recently attracted extensive interest
not
only in the field of healthcare monitoring but also for convenient
and intelligent human–machine interactions. However, challenges
such as wearable comfort, multiple applicable conditions, and differentiation
of mechanical stimuli are yet to be fully addressed. Herein, we developed
a breathable and waterproof electronic skin (E-skin) that can perceive
pressure/strain with nonoverlapping signals. The synergistic effect
from magnetic attraction and nanoscaled aggregation renders the E-skin
with microscaled pores for breathability and three-dimensional microcilia
for superhydrophobicity. Upon applied pressure, the bending of conductive
microcilia enables sufficient contacts for resistance decrease, while
the stretching causes increased resistance due to the separation of
conductive materials. The optimized E-skin exhibits a high gauge factor
of 7.747 for small strain (0–80%) and a detection limit down
to 0.04%. The three-dimensional microcilia also exhibit a sensitivity
of −0.0198 kPa–1 (0–3 kPa) and a broad
detection range up to 200 kPa with robustness. The E-skin can reliably
and precisely distinguish kinds of the human joint motions, covering
a broad spectrum including bending, stretching, and pressure. With
the nonoverlapping readouts, ternary inputs “1”, “0”,
and “–1” could be produced with different stimuli,
which expands the command capacity for logic outputs such as effective
Morse code and intuitive robotic control. Owing to the rapid response,
long-term stability (10 000 cycles), breathability, and superhydrophobicity,
we believe that the E-skin can be widely applied as wearable devices
from body motion monitoring to human–machine interactions toward
a more convenient and intelligent future.
Microbially induced calcite precipitation (MICP) has emerged as a novel soil improvement method. In this paper, 3-D discrete element method (DEM) simulations are used to explore the behavior of MICP-cemented sands. Comparisons of the macro-scale response of numerical and physical specimens are made. Microstructure analyses indicate a shear band formed in the numerical specimens, consistent with physical experiments. The bond breakage pattern in numerical specimens is explored and compared to observed measurements from physical specimens. The relationship between dilatancy and stress-strain behavior is evaluated. The results indicate DEM is an effective technique to capture the mechanical behavior of MICP-cemented sand.
We report the construction of novel temperature-responsive assemblies based on a double hydrophilic block copolymer (consisting of a PEG block and a b-cyclodextrin-containing block, PEG-b-PCD) and poly(N-isopropylacrylamide) (PNIPAm). Thus formed nano-assemblies exhibit a spherical morphology and have a temperature-responsive loose core. The driving force for the formation of these assemblies was found to be the inclusion complexation interaction between the hydrophobic cavity of b-cyclodextrin and the isopropyl group of PNIPAm. The particle size of these assemblies changed reversibly in response to the external temperature change. The particle size also changed with the PNIPAm/PEG-b-PCD weight ratio. A model hydrophobic drug (indomethacin) was loaded into these assemblies with a high efficiency. An in vitro release study showed that the payload could be released in a sustained manner after an initial burst release. The release rate could be switched between high and low in an On/Off fashion by temperature. These results demonstrate that the nano-assemblies have high potential for applications in controlled drug delivery and biomedicine when temperature responsiveness is desired.
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