Two aspects of interfacial phenomena were discussed in the manuscript. The first one concerns the adsorptive removal of two azo dyes such as C.I. Acid Yellow 219 (AY219) and C.I. Direct Yellow 142 (DY142) as well as the phtalocyanine C.I. Reactive Blue 21 (RB21) on the alumina-silicatitania oxide (4% wt. Al2O3-8% wt. SiO2-88% wt. TiO2; AST88) in the ionic surfactants presence. The second one deals with the determination of interaction mechanism in the dyes-AST88, dyes-surfactant-AST88 systems using the data obtained from the surface charge density and zeta potential studies. The sodium dodecyl sulphate (SDS) with anionic character and hexadecyltrimethylammonium bromide (CTAB) with cationic ones were used. The adsorption capacities of 205.2 mg/g for AY219, 36.5 mg/g for RB21 and 18 mg/g for DY142. The potentiometric titration and Doppler laser electrophoresis methods enable determination of sign and magnitude of charge located in both the surface and the slipping plane layers around the solid particles. The structure of electrical double layer was determined in the AST88 systems without as well as with dyes and with mixed dye + surfactant adsorbates.
The study investigates thin-walled steel elements in a form of openwork beams with holes described by variable geometrical parameters. The specimens are modeled numerically and additionally subjected to axial compression in order to examine the critical and post-critical behavior of the thin-walled profiles. The models of profiles are propped articulatedly on the edges of the cross-section in the upper and lower parts. The numerical analysis investigates only the problem of non-linear stability of these structures. The FEM analysis is stopped at the moment when the compressed profiles achieve the yield stress in order to determine their loss of stability without undesired strains. The numerical computations are performed using the ABAQUS ® program to investigate the impact of diameter variability in the thin-walled profiles with holes under allowable operational loads. The numerical investigation was performed only with respect to elastic work, ensuring the stability of thin-walled structures.
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