This colloquium gives an overview of recent theoretical and experimental progress in the area of nonequilibrium dynamics of isolated quantum systems. We particularly focus on quantum quenches: the temporal evolution following a sudden or slow change of the coupling constants of the system Hamiltonian. We discuss several aspects of the slow dynamics in driven systems and emphasize the universality of such dynamics in gapless systems with specific focus on dynamics near continuous quantum phase transitions. We also review recent progress on understanding thermalization in closed systems through the eigenstate thermalization hypothesis and discuss relaxation in integrable systems. Finally we overview key experiments probing quantum dynamics in cold atom systems and put them in the context of our current theoretical understanding.

We describe the localization transition of superfluids on two-dimensional lattices into commensurate Mott insulators with average particle density p/q (p, q relatively prime integers) per lattice site. For bosons on the square lattice, we argue that the superfluid has at least q degenerate species of vortices which transform under a projective representation of the square lattice space group (a PSG). The formation of a single vortex condensate produces the Mott insulator, which is required by the PSG to have density wave order at wavelengths of q/n lattice sites (n integer) along the principle axes; such a second-order transition is forbidden in the Landau-Ginzburg-Wilson framework. We also discuss the superfluid-insulator transition in the direct boson representation, and find that an interpretation of the quantum criticality in terms of deconfined fractionalized bosons is only permitted at special values of q for which a permutative representation of the PSG exists. We argue (and demonstrate in detail in a companion paper: L. Balents et al., cond-mat/0409470) that our results apply essentially unchanged to electronic systems with short-range pairing, with the PSG determined by the particle density of Cooper pairs. We also describe the effect of static impurities in the superfluid: the impurities locally break the degeneracy between the q vortex species, and this induces density wave order near each vortex. We suggest that such a theory offers an appealing rationale for the local density of states modulations observed by Hoffman et al. (cond-mat/0201348) in STM studies of the vortex lattice of BSCCO, and allows a unified description of the nucleation of density wave order in zero and finite magnetic fields. We note signatures of our theory that may be tested by future STM experiments.Comment: 35 pages, 16 figures; (v2) part II is cond-mat/0409470; (v3) added new appendix and clarifying remarks; (v4) corrected typo

We study the quantum dynamics of a number of model systems as their coupling constants are changed rapidly across a quantum critical point. The primary motivation is provided by the recent experiments of Greiner et al. (Nature 415, 39 (2002)) who studied the response of a Mott insulator of ultracold atoms in an optical lattice to a strong potential gradient. In a previous work (cond-mat/0205169), it had been argued that the resonant response observed at a critical potential gradient could be understood by proximity to an Ising quantum critical point describing the onset of density wave order. Here we obtain numerical results on the evolution of the density wave order as the potential gradient is scanned across the quantum critical point. This is supplemented by studies of the integrable quantum Ising spin chain in a transverse field, where we obtain exact results for the evolution of the Ising order correlations under a time-dependent transverse field. We also study the evolution of transverse superfluid order in the three dimensional case. In all cases, the order parameter is best enhanced in the vicinity of the quantum critical point.Comment: 10 pages, 6 figure

For certain orientations of Josephson junctions between two px-wave or two d-wave superconductors, the subgap Andreev bound states produce a 4π-periodic relation between the Josephson current I and the phase difference φ: I ∝ sin(φ/2). Consequently, the ac Josephson current has the fractional frequency eV /h, where V is the dc voltage. In the tunneling limit, the Josephson current is proportional to the first power (not square) of the electron tunneling amplitude. Thus, the Josephson current between unconventional superconductors is carried by single electrons, rather than by Cooper pairs. The fractional ac Josephson effect can be observed experimentally by measuring frequency spectrum of microwave radiation from the junction. We also study junctions between singlet s-wave and triplet px-wave, as well as between chiral px ± ipy-wave superconductors.

The singlet s-, d-and triplet p-wave pairing symmetries in quasi-one-dimensional organic superconductors can be experimentally discriminated by probing the Andreev bound states at the sample edges. These states have the energy in the middle of the superconducting gap and manifest themselves as a zero-bias peak in tunneling conductance into the corresponding edge. Their existence is related to the sign change of the pairing potential around the Fermi surface. We present an exact self-consistent solution of the edge problem showing the presence of the midgap states for px-wave superconductivity. The spins of the edge state respond paramagnetically to a magnetic field parallel to the vector d that characterizes triplet pairing.

We present a strong-coupling expansion of the Bose-Hubbard model which describes both the superfluid and the Mott phases of ultracold bosonic atoms in an optical lattice. By performing two successive HubbardStratonovich transformations of the intersite hopping term, we derive an effective action which provides a suitable starting point to study the strong-coupling limit of the Bose-Hubbard model. This action can be analyzed by taking into account Gaussian fluctuations about the mean-field approximation as in the Bogoliubov theory of the weakly interacting Bose gas. In the Mott phase, we reproduce results of previous mean-field theories and also calculate the momentum distribution function. In the superfluid phase, we find a gapless spectrum and compare our results with the Bogoliubov theory.

Recent experiments on ultracold atomic gases in an optical lattice potential have produced a Mott insulating state of Rb atoms. This state is stable to a small applied potential gradient (an `electric' field), but a resonant response was observed when the potential energy drop per lattice spacing (E), was close to the repulsive interaction energy (U) between two atoms in the same lattice potential well. We identify all states which are resonantly coupled to the Mott insulator for E close to U via an infinitesimal tunneling amplitude between neighboring potential wells. The strong correlation between these states is described by an effective Hamiltonian for the resonant subspace. This Hamiltonian exhibits quantum phase transitions associated with an Ising density wave order, and with the appearance of superfluidity in the directions transverse to the electric field. We suggest that the observed resonant response is related to these transitions, and propose experiments to directly detect the order parameters. The generalizations to electric fields applied in different directions, and to a variety of lattices, should allow study of numerous other correlated quantum phases.Comment: 17 pages, 14 figures; (v2) minor additions and new reference

We describe the zero-temperature phase diagram of a model of bosons, occupying sites of a linear chain, which obey a hard-exclusion constraint: any two nearest-neighbor sites may have at most one boson. A special case of our model was recently proposed as a description of a "tilted" Mott insulator of atoms trapped in an optical lattice. Our quantum Hamiltonian is shown to generate the transfer matrix of Baxter's hard-square model. Aided by exact solutions of a number of special cases, and by numerical studies, we obtain a phase diagram containing states with long-range density-wave order with period 2 and period 3, and also a floating incommensurate phase. Critical theories for the various quantum phase transitions are presented. As a byproduct, we show how to compute the Luttinger parameter in integrable theories with hard-exclusion constraints.