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Fluoride in high concentration in groundwater has been reported from many parts of India. However, a systematic study is required to understand the behavior of fluoride in natural water in terms of local hydrogeological setting, climatic conditions, and agricultural practices. The present study is an attempt to assess hydrogeochemistry of groundwater in parts of Palar river basin pertaining to Kancheepuram district Tamil Nadu to understand the fluoride abundance in groundwater and to deduce the chemical parameters responsible for the dissolution activity of fluoride. The study area is geologically occupied by partly sedimentary and partly crystalline formations. A total of 50 dug cum borewell-water samples, representing an area of 2,628.92 km2. The results of the chemical analyses in September 2009 show fluoride abundance in the range of 1 to 3.24 mg/l with 86% of the samples in excess of the permissible limit of 1.5 mg/l. Presence of fluoride-bearing minerals in the host rock, chemical properties like decomposition, dissociation, and dissolution, and their interaction with water are considered to be the main causes for fluoride in groundwater. Chemical weathering with relatively high alkalinity favors high concentration of fluoride in groundwater. Villagers who consume nonpotable high fluoride water may suffer from yellow, cracked teeth; joint pains; and crippled limbs and also age rapidly.

Remote sensing and geographical information system (GIS) has become one of the leading tools in the field of groundwater research, which helps in assessing, monitoring, and conserving groundwater resources. This paper mainly deals with the integrated approach of remote sensing and GIS to delineate groundwater potential zones in hard rock terrain. Digitized vector maps pertaining to chosen parameters, viz. geomorphology, geology, land use/land cover, lineament, relief, and drainage, were converted to raster data using 23 m×23 m grid cell size. Moreover, curvature of the study area was also considered while manipulating the spatial data. The raster maps of these parameters were assigned to their respective theme weight and class weights. The individual theme weight was multiplied by its respective class weight and then all the raster thematic layers were aggregated in a linear combination equation in Arc Map GIS Raster Calculator module. Moreover, the weighted layers were statistically modeled to get the areal extent of groundwater prospects with respect to each thematic layer. The final result depicts the favorable prospective zones in the study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains.

An attempt has been made in this research work to evaluate the concentration of nitrate in groundwater and its management in Apple town and its environs. Groundwater pollution has been reported in many aquifers because of high concentration of nitrate in ground water, which is the result of excessive use of fertilizers to cropland. Systematic sampling was done, with a view to understand the source of nitrate concentration in the study area. Fifteen sample sites were selected and the samples were taken for a baseline study to understand the geochemistry of the study area and to assess its physicochemical characteristics. The water quality parameters were investigated for summer (May, 2007) and winter (December, 2007) seasons and were compared with the standard values given by ICMR / WHO. The hydrochemical data of 15 samples indicates that the concentration of almost all parameters fall within the permissible limits except nitrate. Linear Trend Analysis on seasonal and annual basis clearly depicted that nitrate pollution in the study area is increasing significantly. About 85% of samples during summer season and 67% of the samples during winter season were showing a high concentration of nitrate, exceeding permissible limit of WHO (50 mg/l), which is due to the use of nitrogenous fertilizers in the study area. Appropriate methods for improving the water quality and its management in the affected areas have been suggested.

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Understanding the groundwater quality is important as it is the main factor determining its suitability for drinking, domestic, agricultural, and industrial purposes. In order to assess the groundwater quality, 30 groundwater samples have been collected in year 2008. The water samples collected in the field were analyzed for electrical conductivity, pH, total dissolved solids (TDS), major cations like calcium, magnesium, sodium, potassium, and anions like bicarbonate, carbonate, chloride, nitrate, and sulfate, in the laboratory using the standard methods given by the American Public Health Association. The groundwater locations were selected to cover the entire study area and attention was been given to the area where contamination is expected. The expected groundwater contaminants were chloride, nitrate, TDS, etc. The results were evaluated in accordance with the drinking water quality standards given by the World Health Organization (WHO 1993). To know the distribution pattern of the concentration of different elements and to demarcate the higher concentration zones, the contour maps for various elements were also generated, discussed, and presented.

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