Abstract:For the first time in hydrochemical conditions tetrathioarsenates of d10-metals by composition Ag 3 AsS 4 and M 3 (AsS 4 ) 2 ·H 2 O, where M-Zn, Cd or Hg and X=(Zn) or 2(Cd, Hg), were synthesized. Their composition, constitution, reaction of dehydration and thermal shock resistance in 20-1000 interval were studied by means of thermal analysis, UR-spectroscopy, X-ray crystal determination and derivatographic research.
Synthesized substances obtained by sodium tetrathioarsenate reaction with silver(I), cobalt (II), mickelous (II), copper (II), zincous, cadmium and mercury have been studied by IR-spectroscopy, X-ray analysis.
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