Equatorial noise (EN) emissions are observed inside and outside the plasmapause. EN emissions are referred to as magnetosonic mode waves. Using data from Van Allen Probes and Arase, we found conversion from EN emissions to electromagnetic ion cyclotron (EMIC) waves in the plasmasphere and in the topside ionosphere. A low‐frequency part of EN emissions becomes EMIC waves through branch splitting of EN emissions, and the mode conversion from EN to EMIC waves occurs around the frequency of M/Q = 2 (deuteron and/or alpha particles) cyclotron frequency. These processes result in plasmaspheric EMIC waves. We investigated the ion composition ratio by characteristic frequencies of EN emissions and EMIC waves and obtained ion composition ratios. We found that the maximum composition ratio of M/Q = 2 ions is ~10% below 3,000 km. The quantitative estimation of the ion composition will contribute to improving the plasma model of the deep plasmasphere and the topside ionosphere.
Thioamidate ions are introduced as competent cocatalysts for multisite proton-coupled electron transfer (MS-PCET) catalysis. The effectiveness of these anions is ascribed to the high pKa values of their conjugate acids. The combined use of bench-stable tetrabutylammonium thioamidate with an appropriate Ir-based photosensitizer allows the C–H alkylation of a range of C–H donors, including simple cyclic alkanes, under visible-light irradiation.
For the purpose of bioinert coating on electronic devices, we developed the non-hydrolytic sol-gel derived organic-inorganic hybrid materials by addition of epoxy groups which can adhere strongly to the surface of electronic silicon device. The adhesion and chemical properties of hybrids were investigated as a function of epoxy group contents. The hybrids were prepared from 3-metacrloxypropyltrimethoxysilane (MPTS) and 3-glycidoxypropyltrimethoxysilane (GPTS) and diphenylsilanediol. The transparent hybrids were obtained after curing by UV irradiation. The adhesion properties of the hybrids were estimated by the maximum load to resist in a scratch test. The adhesion property of the hybrids increased with addition of GPTS and the highest adhesion was obtained from the hybrid with 5-10 mol% of GPTS. From the element analysis, Si concentrations of all the solutions were less than 2 mM after soaking for 7 d. The Si concentrations were not changed with increasing soaking period. The addition of epoxy groups is effective on improvement of adhesion property of the silica-based hybrid without loosening its chemical stability.
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