We report the observation of a Bose-Einstein condensation of ytterbium atoms by evaporative cooling in a novel crossed optical trap. Unlike the previously observed condensates, a ytterbium condensate is a two-electron system in a singlet state and has distinct features such as the extremely narrow intercombination transitions which are ideal for future optical frequency standard and the insensitivity to external magnetic field which is important for precision coherent atom optics, and the existence of the novel metastable triplet states generated by optical excitation from the singlet state.

We report the photoassociation spectroscopy of laser-cooled ytterbium atoms in an optical trap. We observed more than 90 photoassociation resonances of vibrational levels in the (1)Sigma(+)(u) state, including 80 consecutive series, up to 490 GHz detuning with respect to the atomic resonance. From the resonance frequencies we derived the atomic radiative lifetime of the (6s6p) 1P1 state to be 5.464+/-0.005 ns, which is about 2 orders of magnitude improvement over previous results. We also observed line broadening of resonances, which is ascribed to the predissociation to the triplet states, and estimated the transition probability to be 0.2. Furthermore, we observed the decrease of the photoassociation signal intensity, from which the scattering length is estimated to be equal to or less than 3 nm.

We have succeeded in trapping a high density of rare-earth atom of ytterbium (Yb) in a crossed far-off resonance trap. The peak density reaches more than 10(14) cm(-3). With a new method of a delayed crossed far-off resonance trap, we have elucidated that the atoms became concentrated into the cross region by atom-atom collisions. We trap fermionic Yb atoms in the same way as bosonic ones.

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We could recently achieve the Bose Einstein condensation (BEC) of Yb atoms. Yb differs from most of the elements that have previously been condensed, because it is a two-electron atom with the singlet S ground state. Furthermore the Bosonic isotopes of Yb, like 174 Yb which we succeeded to condensate, has no nuclear spin, so that the ground state is completely spin-less state and hence insensitive to magnetic fields. Thus a new type of atom could join the group of atoms for BEC studies. We would like to report how we could achieve the BEC of Yb atoms.

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