Abstract. Air quality networks in cities can be costly and inconsistent and typically
monitor a few pollutants. Space-based instruments provide global coverage
spanning more than a decade to determine trends in air quality, augmenting
surface networks. Here we target cities in the UK (London and Birmingham)
and India (Delhi and Kanpur) and use observations of nitrogen dioxide
(NO2) from the Ozone Monitoring Instrument (OMI), ammonia (NH3)
from the Infrared Atmospheric Sounding Interferometer (IASI), formaldehyde
(HCHO) from OMI as a proxy for non-methane volatile organic compounds
(NMVOCs), and aerosol optical depth (AOD) from the Moderate Resolution
Imaging Spectroradiometer (MODIS) for PM2.5. We assess the skill of
these products at reproducing monthly variability in surface concentrations
of air pollutants where available. We find temporal consistency between
column and surface NO2 in cities in the UK and India (R = 0.5–0.7)
and NH3 at two of three rural sites in the UK (R = 0.5–0.7) but not
between AOD and surface PM2.5 (R < 0.4). MODIS AOD is
consistent with AERONET at sites in the UK and India (R ≥ 0.8) and
reproduces a significant decline in surface PM2.5 in London (2.7 % a−1) and Birmingham (3.7 % a−1) since 2009. We derive long-term
trends in the four cities for 2005–2018 from OMI and MODIS and for 2008–2018
from IASI. Trends of all pollutants are positive in Delhi, suggesting no air
quality improvements there, despite the roll-out of controls on industrial and
transport sectors. Kanpur, identified by the WHO as the most polluted city
in the world in 2018, experiences a significant and substantial (3.1 % a−1) increase in PM2.5. The decline of NO2, NH3, and PM2.5 in London and Birmingham is likely due in large part to emissions controls
on vehicles. Trends are significant only for NO2 and PM2.5.
Reactive NMVOCs decline in Birmingham, but the trend is not significant.
There is a recent (2012–2018) steep (> 9 % a−1) increase
in reactive NMVOCs in London. The cause for this rapid increase is
uncertain but may reflect the increased contribution of oxygenated volatile organic compounds (VOCs) from
household products, the food and beverage industry, and domestic wood
burning, with implications for the formation of ozone in a VOC-limited city.
Tropical cities are experiencing rapid growth but lack routine air pollution monitoring to develop prescient air quality policies. Here, we conduct targeted sampling of recent (2000s to 2010s) observations of air pollutants from space-based instruments over 46 fast-growing tropical cities. We quantify significant annual increases in nitrogen dioxide (NO
2
) (1 to 14%), ammonia (2 to 12%), and reactive volatile organic compounds (1 to 11%) in most cities, driven almost exclusively by emerging anthropogenic sources rather than traditional biomass burning. We estimate annual increases in urban population exposure to air pollutants of 1 to 18% for fine particles (PM
2.5
) and 2 to 23% for NO
2
from 2005 to 2018 and attribute 180,000 (95% confidence interval: −230,000 to 590,000) additional premature deaths in 2018 (62% increase relative to 2005) to this increase in exposure. These cities are predicted to reach populations of up to 80 million people by 2100, so regulatory action targeting emerging anthropogenic sources is urgently needed.
A thermoluminescent dosimeter badge has been designed for use in a countrywide personnel monitoring program. The badge is based on CaS0,:Dy phosphorembedded Teflon TLD discs. A set of metal filters has been incorporated in the badge to compensate for the energy-dependent response of the CaSOs:Dy phosphor at low photon energies. An open-window region has been provided for estimating beta dose. The response of the badge to beta and gamma radiation, its energy and angular dependence, and its reusability in a number of repeated cycles of measurements are discussed.
With decreasing post‐annealing temperature in the region 300 to 220 °C, the sensitization factor of TL glow peak 5 in LiF TLD‐100 is found to decrease systematically from a value of 8 to 3. This is accompanied by a marked increase of intensity of the residual TL peaks occuring in the region 250 to 320 °C. This is a positive indication of the conversion, on thermal annealing, of trap centres responsible for the residual TL to those responsible for the sensitisation. The mechanism of sensitization is otherwise similar to that proposed by Nink and Kos. The sensitization factor of peak 6 (250 °C) is found nearly 3.5 times higher than that of peak 5 (195 °C). This observation confirms Attix's theory of increased range of hole migration at higher temperatures. The model of Kos and Nink, after taking into account the influence of residual TL at low postannealing temperatures, is found to explain satisfactorily the photostimulated TL in LiF. The increased supralinearity of photo‐TL as compared to the TL due to γ‐rays is attributed to the difference in the relative spatial distribution of trap centres and luminescence centres.
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