The FeIII and the CuII‐atom in the complexes 1 and 2 shown below are antiferromagnetically and ferromagnetically coupled, respectively. This difference in the coupling interaction can be correlated with the orientation of the orbital at CuII responsible for the magnetism relative to the bridging phenolate O‐atom. L = 2 6‐bis[(bis(2‐pyridylmethyl)amino(methyl))]‐4‐methylphenol.
Antiferromagnetisch bzw. ferromagnetisch gekoppelt sind das FeIII‐ und das CuII‐Atom in den unten schematisch dargestellten Komplexen 1 und 2. Dieser Unterschied in der Kopplungswechselwirkung kann am bestem mit der Orientierung des für den Magnetismus zuständigen Orbitals am CuII relativ zum verbrückenden Phenolat‐O‐Atom in Einklang gebracht werden. L = 2,6‐bis‐[(bis(2‐pyridylmethyl)amino)methyl)]‐4‐methylphenol.magnified image
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