International audienceThis work proposes a multi-scale study of the properties of leaf sheath date palm fibres currently considered as agricultural waste. Firstly, by using optical and electronic microscopy, two main types of bundles were identified which have profoundly different structures. Biochemical analysis and X-ray diffraction (XRD) revealed a low degree of crystallinity but a significant lignin content of about 17% giving the bundles a very cohesive structure as well as a good thermal stability in addition to a singular behaviour in dynamic vapour sorption. An average cell wall stiffness in the order of 16 GPa was highlighted by Atomic Force Microscopy in mechanical mode but tensile tests on bundles have revealed low stiffness and strength but a high elongation. These results combined with the cellular structure of these bundles, provides the potential of these wastes as cost effective and environmentally friendly composite reinforcements for high energy absorption and improved acoustics functions. (C) 2017 Elsevier Ltd. All rights reserved
In this study, a gradually increased hydro-mechanical treatments duration were applied to native hemp bast fibres with a traditional pulp and paper beating device (laboratory Valley beater). There is often a trade-off between the treatment applied to the fibres and the effect on their integrity. The multimodal analysis provided an understanding of the beating impact on the fibres at multiple scales and the experimental design made it possible to distinguish the effects of hydro-and hydromechanical treatment. Porosity analyses showed that beating treatment doubled the macroporosity and possibly reduced nanoporosity between the cellulose microfibrils. The beating irregularly extracted the amorphous components known to be preferentially located in the middle lamellae and the primary cell walls rather than in the secondary walls, the overall increasing the crystallinity of cellulose from 49.3 % to 59.1 %, but a non-significant change in the indentation moduli of the cell wall was observed. In addition, beating treatments with two distinct mechanical severities showed a disorganization of the cellulose conformation, which significant dropped the indention moduli by 11.2 GPa and 8.4 GPa for 10 and 20 minutes of Valley beater hydromechanical treatment, respectively, compared to hydro-treated hemp fibres (16.6 GPa). Pearson's correlation coefficients between physicochemical features and the final indentation moduli were calculated. Strong positive correlations were highlighted between the cellulose crystallinity and rhamnose, galactose and mannose as non-cellulosic polysaccharide components of the cell wall.
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