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The detailed crystal structure of cubic Li7La3Zr2O12 has been successfully determined by single-crystal X-ray structure analysis. The three-dimensional network of the Li-ion migration pathway with short Li–Li distance and occupational disordering is formed in the garnet-type framework structure. The basic unit of the pathway can be expressed as a loop constructed by the Li1 and Li2 sites. The loop links to another one, where only the Li1 site is shared by two loops as a junction.

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meantimc the first successful crystal structure analysis of a "cobaltocenium-Angiw Ciiem. Int Ed. Engl. 1995, 34, No. 11 VCH Verlag.~gesrllsciiaft mbH, 0-6945'1 Weinheim. 1995 Oj70-0833,'95/1111-1201 B l~l.Ofl+ ..?j:(I

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