Based on the assumption of weak dissipation introduced by Esposito et al. [Phys. Rev. Lett. 105, 150603 (2010)], analytic expressions for the efficiency bounds of several classes of typical thermodynamic cycles at the maximum power output are derived. The results obtained are of universal significance. They can be used to conveniently reveal the general characteristics of not only Carnot heat engines, but also isothermal chemical engines, non-Carnot heat engines, flux flow engines, gravitational engines, quantum Carnot heat engines, and two-level quantum Carnot engines at the maximum power output and to directly draw many important conclusions in the literature.

An atom-economical method for radical (phenylsulfonyl)difluoromethylation of isocyanides with PhSOCFH under transition-metal-free conditions has been developed. A PhSOCF radical is generated through the oxidation of PhSOCF after the deprotonation of PhSOCFH in one pot. The reaction exhibits excellent functional-group tolerance and the resulting products can be further modified with the removal of a PhSO group to give other CF-containing compounds.

The deoxyfluorination of alcohols is a fundamentally important approach to access alkyl fluorides, and thus the development of shelf‐stable, easy‐to‐handle, fluorine‐economical, and highly selective deoxyfluorination reagents is highly desired. This work describes the development of a crystalline compound, N‐tosyl‐4‐chlorobenzenesulfonimidoyl fluoride (SulfoxFluor), as a novel deoxyfluorination reagent that possesses all of the aforementioned merits, which is rare in the arena of deoxyfluorination. Endowed by the multi‐dimensional modulating ability of the sulfonimidoyl group, SulfoxFluor is superior to 2‐pyridinesulfonyl fluoride (PyFluor) in fluorination rate, and is also superior to perfluorobutanesulfonyl fluoride (PBSF) in fluorine‐economy. Its reaction with alcohols not only tolerates a wide range of functionalities including the more sterically hindered alcoholic hydroxyl groups, but also exhibits high fluorination/elimination selectivity. Because SulfoxFluor can be easily prepared from inexpensive materials and can be safely handled without special techniques, it promises to serve as a practical deoxyfluorination reagent for the synthesis of various alkyl fluorides.

No abstract

A relationship between stability and self-optimization is found for weakly dissipative heat devices. The effect of limited control on operation variables around an steady state is such that, after instabilities, the paths toward relaxation are given by trajectories stemming from restitution forces which improve the system thermodynamic performance (power output, efficiency, and entropy generation). Statistics over random trajectories for many cycles shows this behavior as well. Two types of dynamics are analyzed, one where an stability basin appears and another one where the system is globally stable. Under both dynamics there is an induced trend in the control variables space due to stability. In the energetic space this behavior translates into a preference for better thermodynamic states, and thus stability could favor self-optimization under limited control. This is analyzed from the multiobjective optimization perspective. As a result, the statistical behavior of the system is strongly influenced by the Pareto front (the set of points with the best compromise between several objective functions) and the stability basin. Additionally, endoreversible and irreversible behaviors appear as very relevant limits: The first one is an upper bound in energetic performance, connected with the Pareto front, and the second one represents an attractor for the stochastic trajectories.

No abstract

In order to investigate the performance of a class of thermally driven refrigerators, usually driven by low-grade thermal energy, a generic thermodynamic model of three-heat-source refrigerator without involving any specific heat-transfer law is put forward by adopting low-dissipation assumptions. Based on the proposed model, the analytical expressions for the coefficient of performance (COP) and cooling power of the system are derived in terms of well-defined dissipation parameters and contact time durations between the system and heat reservoirs. One essential parameter accounting for the size ratio of the two coupled subsystems inside the overall system is introduced in light of the practical meaning of the reversible entropy change. With the help of the aforementioned parameter, the optimal relation between the COP and cooling power is obtained. The optimal operation region and optimal construction of the overall system are further determined for the first time. In addition, the influences of the dissipation and temporal symmetries are discussed in detail, according to which the upper and lower bounds of the COP at maximum cooling power are firstly obtained under two extreme situations. Experimental and simulated data from previous reported works are collected to illustrate the validity and practical significance of the proposed model and associated results. A limit case is presented to highlight the generality of the model.

A 24-year-old, spayed female Malayan sun bear (Helarctos malayanus) in the Taipei Zoo (Taipei, Taiwan) showed clinical signs of slowly progressive anorexia, dullness, compulsive pacing, and circling. The animal subsequently developed acute severe stupor and persistent recumbency. Postcontrast study of computed tomography revealed a spheroid, extra-axial mass with strong but heterogeneous hyperattenuation in the left temporal lobe of the cerebrum. At necropsy, a solitary, well-circumscribed intracranial mass measuring 3 cm × 2.5 cm × 2 cm was attached to the left pyriform lobe with compression of the adjacent neuroparenchyma. Cytological examination obtained from the mass revealed large clumps and sheets of cohesive polyhedral cells with round nuclei, wispy cytoplasm, and indistinct cell borders. Microscopically, the mass was composed of densely packed round to polygonal cells arranged in lobules and small nests. Psammoma bodies, xanthomatous change, and cholesterol deposition were also noted. Immunohistochemical staining of the tumor was positive for vimentin, pancytokeratin, cytokeratin (CK)34BE12, neuron-specific enolase, and epithelial membrane antigen, but negative for glial fibrillary acidic protein and S100 protein. The cytological, histological, and immunohistochemical features were compatible with a meningothelial meningioma.