An organic ester p -nitrobenzyl acetate (PNBA) was synthesized and used to establish a kind of autogenic acid system through the hydrolysis of ester to acetic acid in situ. The autogenic acid system can form a homogeneous solution by adding an organic solvent. The autogenic acid system possesses the desired characteristic in which hydrolysis can generate a small amount of acetic acid below 120 °C and a large amount of acid above 140 °C in 2 h. The acid-generated ability at different time and temperature was studied in detail. The dissolution of solid calcium carbonate and carbonate rocks by the autogenic acid system was investigated. The autogenic acid displayed lower dissolution ability on a carbonate rock and weak corrosion of a N80 steel sheet at 150 °C. The autogenic acid is especially suitable for acid fracturing and dissolution of rocks in a high-temperature carbonate reservoir.
The eastern margin of the Qinghai-Tibet Plateau (QTP) is the focus of studies on eastward lateral extrusion of the latter's crustal material. This study aims to explore the structural response of the QTP's eastern crust-mantle to the extrusion, and the basis for the latter's geological structure. Data on the long-period magnetotelluric sounding of cross-tectonic units and Bouguer gravity were used to determine the physical structure of the crust-mantle at the plateau's eastern margin. The findings are as follows: (i) the apparent density structure indicates the large presence of a low-density material in the middle-lower crusts of the Songpan and Sichuan-Yunnan blocks at the QTP's eastern margin. On the other hand, the Yangtze cratonic block (Sichuan Basin) contains a material with a significantly higher density. To the west of the Longmenshan-Panxi tectonic zones, and along the lower crust at 40-50 km depth, is an obvious low-density zone aligned in a northeast-southwest orientation. (ii) The electrical structural model spanning Songpan block-Longmenshan tectonic zone-Yangtze block reveals three distinct electrical structural units along the cross-section bounded by the Longmenshan tectonic zone. The first is the Songpan block, which has high and low resistivity at the superficial layer and middle-lower crusts, respectively. Next is the Yangtze craton, which has a low and relatively higher resistivity at the superficial layer and middle-lower crusts, respectively. The third is the Longmenshan transitional tectonic zone, whose shallow layer and deep structure are characterized by an electrical structure with a thrust nappe towards the east, and a high-conductivity material extending to the lithospheric mantle, respectively. (iii) The apparent density and electrical structures indicate that the Panxi tectonic zone has a weakened structure in the lower crust; and (iv) physical properties of the QTP's deep structure show that its eastern margin may contain a middle-lower crustal fluid material with the attributes of high conductivity and low density. Its distribution is interrelated to the uplift mechanism and deep seismogenic activities at the QTP's eastern margin. El margen oriental del altiplano Qinghai-Tíbet (QTP, del inglés Qinghai-Tibet Plateau) es el área de la extrusión lateral hacia el Este de material cortical. Este trabajo se enfoca en explorar la respuesta estructural de las capas superiores en el altiplano y las bases para su estructuracón geológica. Se utilizó información magnetotelúria y anomalías de Bouguer para determinar la respuesta geofísica de las capas superiores en el margen occidental del altiplano. Dentro de los principales resultados se tiene: (i) la distribución de la densidad aparente indica la presencia de material de baja densidad en las capas medias y bajas de los bloques Songpan y Sichuan-Yunnan en el Este del QTP. Por otro lado, el bloque cratónico Yangtze (en la cuenca Sichuan) contiene material con una mayor densidad. Al oeste de las zonas tectónicas Longmeshan-Panxi, y a lo largo...
The unconventional reservoirs such as carbonate formation develops complex and diverse storage space structures, and it is composed of large-scale cavity, dissolved vug, and fractures. The carbonate reservoir is highly heterogeneous. Acid fracturing of carbonate reservoir is completed through the complex mechanical mechanism of interaction between vug and hydraulic fracture (HF). We use the equivalent method of reducing the rock strength by acid etching and serious fluid leakoff during interaction of HF and vug to establish a finite element (FE) model of HF propagation during acid fracturing in the fractured-vuggy carbonate reservoir. The model considers the effect of serious fluid leakoff during interaction between HF and vug, mechanism of interaction between HFs and the fracture-vug system, and change in acid etching intensity. Then, we carry out numerical simulation on impacts of injection rate, fluid viscosity, leakoff behavior in fractures and vugs, and natural fracture (NF) approaching angle on HF propagation in acid fracturing and compare the characteristics of injection pressure, fracture pressure, and HF size. It is suggested that the acid fracturing treatment should be operated by increasing the acid solution viscosity to reduce fluid leakoff, injecting fracturing fluid and acid fluid alternatively, increasing injection rate, and injecting fibers and ceramics when small pressure drop occurs during the HF interacts with the fracture-vug. When a large pressure drop occurs, it is suggested that the middle-low viscosity acid be injected at a low rate to etch the carbonate rock and enhance the fracture conductivity. HF propagates under higher pressure when the NF approaching angle is smaller.
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