The synthesis of Na x K y Fe[Fe(CN) 6 ] through a simple co-precipitation method and the application of these nanoparticles in sodium-ion batteries are presented. K 1.90 Fe[Fe(CN) 6 ] with a cubic structure shows low volumetric change during electrochemical cycling. It is clarified by ex-situ X-ray diffraction and cyclic voltammetry curves that K + influences the intercalation sites of the neighboring Na +. More significantly, this hexacyanoferrate delivers a high capacity of 137.0 mAh g − 1 at a current density of 14 mA g − 1 and superior cyclability with 94% capacity retention after 120 cycles, showing great promise for sodium-ion battery applications.
Understanding and controlling interface friction are central to many science and engineering applications. However, frictional sliding is closely related to adhesion, surface roughness, surface chemistry, mechanical deformation of contact solids, which poses the major challenge to experimental studying and theoretical modeling of friction. Here, by exploiting the recent developed thermomechanical nanomolding technique, we present a simple strategy to decouple the interplay between surface chemistry, plastic deformation, and interface friction by monitoring the nanoscale creep flow of metals in nanochannels. We show that superhydrophobic nanochannels outperforming hydrophilic nanochannels can be up to orders of magnitude in terms of creep flow rate. The comparative experimental study on pressure and temperature dependent nanomolding efficiency uncovers that the enhanced creep flow rate originates from diffusion-based deformation mechanism as well as the superhydrophobic surface induced boundary slip. Moreover, our results reveal that there exists a temperature-dependent critical pressure below which the traditional lubrication methods to reduce friction will break down. Our findings not only provide insights into the understanding of mechanical deformation and nanotribology, but also show a general and practical technique for studying the fundamental processes of frictional motion. Finally, we anticipate that the increased molding efficiency could facilitate the application of nanoimprinting/nanomolding.
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