The dimensions and intermolecular interactions of surface-grafted and unbound, free polyampholytes, poly [3-(N-2-methacryloyloxyethyl-N,N-dimethyl) ammonatopropanesulfonate] (PMAPS) and poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC), were estimated in an aqueous NaCl solution over a wide range of salt concentrations (C s ). The free PMAPS and PMPC fractionated by a recycling preparative size-exclusion chromatography system were characterized in aqueous NaCl solutions for C s over a range from 0 to 5.0 M by static light scattering and dynamic light scattering (DLS) measurements. The hydrodynamic radius (R H ) and the concentration coefficient of the diffusion coefficient (k D ) for PMPC were independent of C s , whereas those for PMAPS were strongly dependent on C s . Monodisperse silica nanoparticles immobilized with PMAPS (SiNP-PMAPS) and PMPC (SiNP-PMPC) by surface-initiated atom transfer radical polymerization were characterized in aqueous NaCl solutions for C s over a range from 0 to 5.0 M by DLS and synchrotron radiation small-angle X-ray scattering (SAXS) measurements. The SAXS profiles from SiNP-PMAPS and SiNP-PMPC solutions were well described by the core-shell model, taking into account interacting self-avoiding chains and assuming a Schulz-distributed core with two fitting parameters.
Tea or coffee? The layer‐by‐layer assembly of mesoporous carbon onto a quartz crystal microbalance results in a structure (see picture) that can be used for highly selective in situ measurement of nonionic aqueous guests, such as tea components.
The 1.5 and 2.4 GHz range 5IDT-type longitudinally coupled surface acoustic wave (SAW) resonator filters have been developed using ZnO/sapphire substrate. The 1.5 GHz range SAW filter has the minimum insertion loss of 1.0 dB and the relative bandwidth of 2.4% at the insertion loss of 3 dB.
The 2.4 GHz range SAW filter has the minimum insertion loss of 1.7 dB and the relative bandwidth of 1.7% at the insertion loss of 3 dB.
These filters are suitable for use as RF-stage filters in a personal digital cellular (PDC) system terminal and a wireless local area network (LAN) adapter, respectively.
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