The demand for fresh and clean water sources increases globally, and there is a need to develop novel routes to eliminate micropollutants and other harmful species from water. Photocatalysis is...

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To optimize yields, the study of reaction kinetics related to the synthesis of 2-hydroxyethylhydrazine (HEH) obtained from the alkylation of N 2 H 4 by 2-chloroethanol (CletOH) was carried out with and without sodium hydroxide. In both cases, the main reaction of HEH formation was followed by a consecutive, parallel reaction of HEH alkylation (or dialkylation of N 2 H 4 ), leading to the formation of two isomers: 1,1-di(hydroxyethyl)hydrazine and 1,2-di(hydroxyethyl)hydrazine. In this study, hydrazine and hydroxyalkylhydrazine alkylations followed S N 2 reactions triggered directly by CletOH or indirectly in the presence of a strong base by ethylene oxide, an intermediate compound. The kinetics was studied in diluted mediums by quantifying HEH and CletOH by gas chromatography and gas chromatography coupled with mass spectrometry (GC-MS). The activation parameters of each reaction and the influence of a strong base present in the medium on the reaction mechanisms were established. A global mathematical treatment was applied for each alternative. It allowed modeling the reactions as a function of reagent concentrations and temperature. In the case of direct alkylation by CletOH, simulation was established for semi-batch and batch syntheses and was confirmed in experiments for concentrated mediums (1.0 M ≤ [CletOH] 0 ≤ 3.2 M and 15.7 M ≤ [N 2 H 4 ] 0 ≤ 18.8 M). Simulation therefore permits the prediction of the instantaneous concentration of reagents and products, in particular ethylene oxide concentration in the case of indirect alkylation, which must be as weak as possible.