In a context promoting waste sustainable management, dredged sediments are assessed for valorization as substitute for sand in non-structural cemented mortars. Full substitution of sand by total sediment revealed low mechanical performances at UCS testing, linked to a high porosity. However, mechanical strength was improved, and porosity reduced, by using 80µmsized sediment. Thus, porosity is correlated to the presence of a fine fraction and its constitution, which brought a higher water demand during formulation. This research confirmed that the reuse of the coarser fraction of a marine sediment offered an interesting valorization potential as cemented mortars for non-structural applications.

Millions of tons of contaminated sediments are dredged each year from the main harbors in France. When removed from water, these sediments are very reactive, therefore their geochemical behavior must be understood in order to avoid dispersion of contaminated lixiviates in the surrounding soils. In this objective, it is necessary to evaluate the principal physicochemical parameters, and also achieve advanced mineralogical characterization. These studied sediments are highly contaminated by metals, notably copper (1445 and 835mg/kg, in the unweathered and naturally-weathered sediments, respectively), lead (760 and 1260mg/kg, respectively), zinc (2085 and 2550mg/kg, respectively), as well as by organic contaminants (PAH, PCB) and organometallics (organotins). A high concentration of sulfide minerals was also observed both in the unweathered sediment preserved under water (3.4wt% of pyrite especially), and in the naturally weathered sediment (2wt% pyrite), and in particular framboïdal pyrite was observed in the two materials. The presence of reactive mineral species in the naturally-weathered sediment can be explained by the deposit of a protective layer, composed of sulfide and their oxidation products (sulfate and iron oxides), thus preventing oxygen from diffusing through to the sulfide minerals. Additionally, the presence of aluminosilicates aggregates coating the sulfide minerals could also explain their presence in the naturally-weathered sediment. As organic matter is one of the principal constituents of the sediments (5.8 and 6.3wt% total organic carbon in the unweathered and weathered sediment, respectively), the aggregates are probably partially constituted of refractory humic material. It therefore appears that the natural weathering has led to a significant decrease in PAHs and organotins, but not in PCBs. The evolution of the granulometric structure and the distribution of the metallic contaminants could therefore lead us to consider a treatment by size separation, and a possible valorization of the dredged sediments in civil engineering.

The S/S process applied using hydraulic binders proved to be efficient in the stabilization of Cu, Pb, and Zn highly presents in studied sediments, and further valorization in civilian engineering applications could be considered.

Contaminated dredged sediments are often considered hazardous wastes, so they have to be adequately managed to avoid leaching of pollutants. The mobility of inorganic contaminants is a major concern. Metal sulfides (mainly framboïdal pyrite, copper, and zinc sulfides) have been investigated in this study as an important reactive metal-bearing phase sensitive to atmospheric oxygen action. An oxygen consumption test (OC-Test) has been adapted to assess the reactivity of dredged sediments when exposed to atmospheric oxygen. An experimental column set-up has been developed allowing the coupling between leaching and oxygen consumption test to investigate the reactivity of the sediment. This reactivity, which consisted of sulfide oxidation, was found to occur for saturation degree between 60 and 90 % and until the 20th testing week, through significant sulfates releases. These latter were assumed to come from sulfide oxidation in the first step of the test, then probably from gypsum dissolution. Confrontation results of OC-Test and leachate quality shows that Cu was well correlated to sulfates releases, which in turn, leads to Ca and Mg dissolution (buffer effect). Cu, and mostly Zn, was associated to organic matter, phyllosilicates, and other minerals through organo-clay complexes. This research confirmed that the OC-Test, originally developed for mine tailings, could be a useful tool in the dredged sediment field which can allow for intrinsic characterization of reactivity of a material suspected to readily reacting with oxygen and for better understanding of geochemical processes that affect pollutants behavior, conversion, and transfer in the environment.

The "greening effect" refers to hardened concrete containing Granulated Blast-Furnace Slag (GBFS) that displays a vivid blue-green color after removal of formwork. This temporary coloration effect, which fades within a few days to weeks, has raised concerns about its potential impact on the environment. Three types of leaching tests were conducted to assess different potential release scenarios: a sprinkling test, a static monolith tank test and a batch test on crushed samples. Slag content was linked to a higher release of sulfur anions in the leachates, in the form of sulfides, thiosulfates and sulfates. Most of these anions came from the GBFS, where sulfur is mainly in the form of sulfides with thiosulfates and sulfates as the main products of sulfide oxidation. Sulfate levels, however, were lower than threshold limit values for both inert waste and alternate materials reused in road construction. Moreover, no chromium, or other hazardous metals, were detected in the leachates.

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