Mechanical energy harvesters are needed for diverse applications, including self-powered wireless sensors, structural and human health monitoring systems, and the extraction of energy from ocean waves. We report carbon nanotube yarn harvesters that electrochemically convert tensile or torsional mechanical energy into electrical energy without requiring an external bias voltage. Stretching coiled yarns generated 250 watts per kilogram of peak electrical power when cycled up to 30 hertz, as well as up to 41.2 joules per kilogram of electrical energy per mechanical cycle, when normalized to harvester yarn weight. These energy harvesters were used in the ocean to harvest wave energy, combined with thermally driven artificial muscles to convert temperature fluctuations to electrical energy, sewn into textiles for use as self-powered respiration sensors, and used to power a light-emitting diode and to charge a storage capacitor.
A scalable and catalyst-free method to deposit stoichiometric molybdenum disulfide (MoS2) films over large areas is reported, with the maximum area limited by the size of the substrate holder. The method allows deposition of MoS2 layers on a wide range of substrates without any additional surface preparation, including single-crystal (sapphire and quartz), polycrystalline (HfO2), and amorphous (SiO2) substrates. The films are deposited using carefully designed MoS2 targets fabricated with excess sulfur and variable MoS2 and sulfur particle size. Uniform and layered MoS2 films as thin as two monolayers, with an electrical resistivity of 1.54 × 10(4) Ω cm(-1), were achieved. The MoS2 stoichiometry was confirmed by high-resolution Rutherford backscattering spectrometry. With the method reported here, in situ graded MoS2 films ranging from ∼1 to 10 monolayers can be deposited.
The experimental study of interlayer sliding at the nanoscale in layered solids has been limited thus far by the incapability of mechanical and imaging probes to simultaneously access sliding interfaces and overcome through mechanical stimulus the van der Waals and Coulombic interactions holding the layers in place. For this purpose, straightforward methods were developed to achieve interlayer sliding in molybdenum disulfide (MoS2) while under observation within a transmission electron microscope. A method to manipulate, tear, and slide free-standing atomic layers of MoS2 is demonstrated by electrostatically coupling it to an oxidized tungsten probe attached to a micromanipulator at a bias above ±7 V. A first-principles model of a MoS2 bilayer polarized by a normal electric field of 5 V/nm, emanating from the tip, demonstrates the appearance of a periodic negative sliding potential energy barrier when the layers slide into the out-of-registry stacking configuration, hinting at electrostatic gating as a means of modifying the interlayer tribology to facilitate shear exfoliation. A method to shear focused ion beam prepared MoS2 cross section samples using a nanoindenter force sensor is also demonstrated, allowing both the observation and force measurement of its interlayer dynamics during shear-induced sliding. From this experiment, the zero normal load shear strength of MoS2 can be directly obtained: 25.3 ± 0.6 MPa. These capabilities enable the site-specific mechanical testing of dry lubricant-based nanoelectromechanical devices and can lead to a better understanding of the atomic mechanisms from which the interlayer tribology of layered materials originates.
Transition metal dichalcogenides (TMDs) are a class of two-dimensional (2D) materials that have attracted growing interest because of their unique electronic and optical properties. Under ambient conditions, most TMDs generally exhibit 2H or 1T structures. Unlike other group VIb TMDs, bulk crystals and powders of WTe2 exist in a distorted 1T structure (Td) at room temperature and have semimetallic properties. There is so far a lack of direct atom-by-atom visualization, limiting our understanding of this distorted 2D layered material system. We present herein atomic resolution images of Td structured WTe2. The Td structure can be distinguished in the three major orientations along the [100], [010], and [001] zone axes. Subtle structural distortions are detected by atomic resolution imaging, which match well with the optimized structure relaxed by ab initio calculations. The calculations also showed that both crystal field splitting and charge density wave (CDW) interactions contribute to the stabilization of WTe2. However, the CDW interaction dominates and leads the Td-WTe2 to be the most stable structure. The combined atomic resolution STEM and ab initio study on WTe2 provided the basis for understanding the correlations between atomic structure and electronic properties in Td structured TMD materials.
Accomplishing slow translocation speed with high sensitivity has been the most critical mission for solid‐state nanopore (SSN) device to electrically detect nucleobases in ssDNA. In this study, a method to detect nucleobases of ssDNA using a 2D SSN is introduced by considerably reducing the translocation speed and effectively increasing its sensitivity. The ultra‐thin titanium dioxide coated hexagonal boron nitride nanopore was fabricated, along with an ionic‐liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate/2.0 M KCl aqueous (cis/trans) interface, for increasing both the spatial and the temporal resolutions. As the ssDNA molecules entered the nanopore, a brief surge of electrical conductivity occurred, which was followed by multiple resistive pulses from nucleobases during the translocation of ssDNA and another brief current surge flagging the exit of the molecule. The continuous detection of nucleobases using a 2D SSN device is a novel achievement: the water molecules bound to ssDNA increased the molecular conductivity and amplified electrical signals during the translocation. Along with the experiment, computational simulations using COMSOL Multiphysics are presented to explain the pivotal role of water molecules bound to ssDNA to detect nucleobases using a 2D SSN.
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