As part of increased efforts to develop wearable healthcare devices for monitoring and managing physiological and metabolic information, stretchable electrochemical sweat sensors have been investigated. In this study, we report on the fabrication of a stretchable and skin-attachable electrochemical sensor for detecting glucose and pH in sweat. A patterned stretchable electrode was fabricated via layer-by-layer deposition of carbon nanotubes (CNTs) on top of patterned Au nanosheets (AuNS) prepared by filtration onto stretchable substrate. For the detection of glucose and pH, CoWO/CNT and polyaniline/CNT nanocomposites were coated onto the CNT-AuNS electrodes, respectively. A reference electrode was prepared via chlorination of silver nanowires. Encapsulation of the stretchable sensor with sticky silbione led to a skin-attachable sweat sensor. Our sensor showed high performance with sensitivities of 10.89 μA mM cm and 71.44 mV pH for glucose and pH, respectively, with mechanical stability up to 30% stretching and air stability for 10 days. The sensor also showed good adhesion even to wet skin, allowing the detection of glucose and pH in sweat from running while being attached onto the skin. This work suggests the application of our stretchable and skin-attachable electrochemical sensor to health management as a high-performance healthcare wearable device.

In this study, we demonstrate the fabrication of a highly sensitive flexible temperature sensor with a bioinspired octopus-mimicking adhesive. A resistor-type temperature sensor consisting of a composite of poly(N-isopropylacrylamide) (pNIPAM)-temperature sensitive hydrogel, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, and carbon nanotubes exhibits a very high thermal sensitivity of 2.6%·°C between 25 and 40 °C so that the change in skin temperature of 0.5 °C can be accurately detected. At the same time, the polydimethylsiloxane adhesive layer of octopus-mimicking rim structure coated with pNIPAM is fabricated through the formation of a single mold by utilizing undercut phenomenon in photolithography. The fabricated sensor shows stable and reproducible detection of skin temperature under repeated attachment/detachment cycles onto skin without any skin irritation for a long time. This work suggests a high potential application of our skin-attachable temperature sensor to wearable devices for medical and health-care monitoring.

This study reports on the fabrication of pressure/temperature/strain sensors and all‐solid‐state flexible supercapacitors using only polydimethylsiloxane coated microporous polypyrrole/graphene foam composite (PDMS/PPy/GF) as a common material. A dual‐mode sensor is designed with PDMS/PPy/GF, which measures pressure and temperature with the changes of current and voltage, respectively, without interference to each other. The fabricated dual‐mode sensor shows high sensitivity, fast response/recovery, and high durability during 10 000 cycles of pressure loading. The pressure is estimated using the thermoelectric voltage induced by simultaneous increase in temperature caused by a finger touch on the sensor. Additionally, a resistor‐type strain sensor fabricated using the same PDMS/PPy/GF could detect the strain up to 50%. Flexible, high performance supercapacitor used as a power supply is fabricated with electrodes of PPy/GF for its high surface area and pseudocapacitance. Furthermore, an integrated system of such fabricated multifunctional sensors and a supercapacitor on a skin‐attachable flexible substrate using liquid–metal interconnections operates well, whereas sensors are driven by the power of the supercapacitor. This study clearly demonstrates that the appropriate choice of a single functional material enables fabrication of active multifunctional sensors for pressure, temperature, and strain, as well as the supercapacitor, that could be used in wirelessly powered wearable devices.

LiCl is a classic "hard" ion salt that is present in lithium-rich brines and a key component in end-of-life materials (that is, used lithium-ion batteries). Its isolation and purification from like salts is a recognized challenge with potential strategic and economic implications. Herein, we describe two ditopic calix[4]pyrrole-based ion-pair receptors (2 and 3), that are capable of selectively capturing LiCl. Under solid-liquid extraction conditions, using 2 as the extractant, LiCl could be separated from a NaCl/KCl salt mixture containing as little as 1 % LiCl with circa 100 % selectivity, while receptor 3 achieved similar separations when the LiCl level was as low as 200 ppm. Under liquid-liquid extraction conditions using nitrobenzene as the non-aqueous phase, the extraction preference displayed by 2 is KCl>NaCl>LiCl. In contrast, 3 exhibits high selectivity towards LiCl over NaCl and KCl, with no appreciable extraction being observed for the latter two salts.

Body-attachable sensors can be applied to electronic skin (e-skin) as well as safety forewarning and health monitoring systems. However, achieving facile fabrication of high-performance, cost-effective sensors with mechanical stability in response to deformation due to body movement is challenging. Herein we report the material design, fabrication and characteristics of a skin-like stretchable array of multi-functional (MF) sensors based on a single sensing material of polyurethane foam coated with multi-walled carbon nanotube/polyaniline nanocomposite, which enables simultaneous detection of body temperature, wrist pulse and ammonia gas. These sensors exhibit high sensitivity, fast response and excellent durability. Furthermore, the fabricated sensor array shows stable performance under biaxial stretching up to 50% and attachment to skin owing to the use of directprinted Galinstan liquid metal interconnections. This work proposes a facile method for fabrication of high-performance, stretchable MF sensors via appropriate selection of sensor design and functional materials that are applicable to e-skin and health monitoring systems. NPG Asia Materials (2017) 9, e448; doi:10.1038/am.2017.194; published online 17 November 2017 INTRODUCTIONWearable electronics have attracted considerable attention for use in electronic skin (e-skin) and health monitoring systems in order for a comfortable and secure life. 1-5 e-Skin is a human interactive device that can simultaneously sense signals from the body and respond to the environment. Thus it should be capable of measuring the five types of senses (taste, sight, hearing, olfactory and touch sensation) with high sensitivity and show mechanical stability against deformation due to skin movement. As a result, e-skin is required to be very thin and have a strain-relaxed design. 6 Because of the increasing importance of e-skin, extensive efforts have been undertaken to develop various sensors with high sensitivity. 7 Beyond the conventional sensor that can detect a single stimulus, novel advanced sensors for simultaneous monitoring of multiple stimuli (multi-functional (MF) sensors) have been actively investigated. 8,9 For practical application of such MF sensors, it is necessary to eliminate the interference between different stimuli that is commonly observed in conventional MF sensors, 10 in addition to fabricating cost-effective sensors on a deformable substrate. Development of MF sensors that transduce different stimuli into separate signals can intrinsically minimize signal interference, thus allowing for sensitive detection of multiple parameters, such as temperature and pressure, in a single device without decoupling analysis. Many power-

A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized.

A synthetic dicationic meso-bis(benzimidazolium) calix[4]pyrrole permits the sensing and chemical capture of CO 2 in its hydrated forms.

In this report, we investigate the rapid heating ability of laser-induced graphene (LIG) in response to radio frequency (RF) fields. Graphitic structures were produced from various industrially prevalent thermoplastics via laser irradiation of the polymer surface. We find that RF responsive, graphitic structures may be produced from Kapton, polyether imide (PEI), polyether sulfone (PESU), polyether ether ketone (PEEK), and polycarbonate (PC) using a conventional laser cutting machine. The graphitic structures are also electrically conductive in addition to being RF responsive. Exposure of LIG to RF fields resulted in the rapid heating of LIG with remarkable heating rates up to 126 °C/s. Finite-element simulations for these systems show similar heating trends. This heating response may be used in advanced manufacturing as a means to rapidly weld polymer–polymer interfaces, as will be demonstrated in this report. Our technique uses RF fields to induce localized heating in contrast to uniform bulk heating from external sources such as ovens or furnaces. The methods detailed in this paper provide a polymer processing pathway that may be used to generate RF responsive filler in situ. Finally, we aim to show that LIG–polymer composites may function in an industrial setting, with particular application to additive manufacturing and functional coatings.