Detection and separation of gas-phase volatile organic compounds (VOCs) is of great importance for many applications including air quality monitoring, toxic gas detection and medical diagnostics. A lack of small...
The selective detection of individual hazardous volatile organic compounds (VOCs) within a mixture is of great importance in industrial contexts due to environmental and health concerns. Achieving this with inexpensive, portable detectors continues to be a significant challenge. Here, a novel thermal separator system coupled with a photoionization detector has been developed, and its ability to selectively detect the VOCs isopropanol and 1octene from a mixture of the two has been studied. The system includes a nanoporous silica preconcentrator in conjunction with a commercially available photoionization detector (PID). The PID is a broadband total VOC sensor with little selectivity; however, when used in conjunction with our thermal desorption approach, selective VOC detection within a mixture can be achieved. VOCs are adsorbed in the nanoporous silica over a 5 min period at 5 °C before being desorbed by heating at a fixed rate to 70 °C and detected by the PID. Different VOCs desorb at different times/temperatures, and mathematical analysis of the set of PID responses over time enabled the contributions from isopropanol and 1-octene to be separated. The concentrations of each compound individually could be measured in a mixture with limits of detection less than 10 ppb v and linearity errors less than 1%. Demonstration of a separation of a mixture of chemically similar compounds, benzene and o-xylene, is also provided.
Increased sensitivity of mid-IR evanescent field sensing for gas-phase volatile organic compound detection using a nano-porous coating of an optical-fibre.
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