Hybrid organic-inorganic perovskites based on methylammonium lead (MAPbI) are an emerging material with great potential for high-performance and low-cost photovoltaics. However, for perovskites to become a competitive and reliable solar cell technology their instability and spatial variation must be understood and controlled. While the macroscopic characterization of the devices as a function of time is very informative, a nanoscale identification of their real-time local optoelectronic response is still missing. Here, we implement a four-dimensional imaging method through illuminated heterodyne Kelvin probe force microscopy to spatially (<50 nm) and temporally (16 s/scan) resolve the voltage of perovskite solar cells in a low relative humidity environment. Local open-circuit voltage (V) images show nanoscale sites with voltage variation >300 mV under 1-sun illumination. Surprisingly, regions of voltage that relax in seconds and after several minutes consistently coexist. Time-dependent changes of the local V are likely due to intragrain ion migration and are reversible at low injection level. These results show for the first time the real-time transient behavior of the V in perovskite solar cells at the nanoscale. Understanding and controlling the light-induced electrical changes that affect device performance are critical to the further development of stable perovskite-based solar technologies.
voltage and the overall electrical behavior of a device strongly depend on the nonradiative recombination rate of the charge carriers within a material, which is affected by the defects inherently present within the semiconductor. Despite all the efforts in developing higher performance thin-fi lm polycrystalline solar cells, such as CdTe, CuIn x Ga (1− x ) Se 2 (CIGS), and Cu 2 ZnSnS 4 (CZTS), the difference between the theoretically predicted and the best experimentally achieved V oc is still considerably large (up to 0.6 V). [ 2,3 ] For Si, extensive research has been dedicated to design and implement nanostructured light-trapping architectures to boost light absorption; [4][5][6][7] however, there are very few experiments showing how the V oc is affected. For organic PV blends, the limited V oc observed in most bulk heterojunction solar cells is attributed to geminate and nongeminate losses; [ 8,9 ] nevertheless, local variations in V oc have never been measured. Thus, for any micrometer-and nanoscale structured PV device, assessing variations in V oc with nanoscale resolution and spatially resolving where recombination occurs within the material can potentially change the pathway for designing higher performance devices.Imaging methods based on atomic force microscopy (AFM) techniques have been extensively used to characterize the structural and electrical properties of PV materials and full devices. [10][11][12][13][14][15][16][17][18][19][20][21] In particular, Kelvin probe force microscopy (KPFM) has been implemented to probe the electrical characteristics of a variety of PV materials and devices, ranging from organic materials [ 9,[22][23][24] and oxides [ 25 ] to III-V semiconductors for multijunction designs [26][27][28] and polycrystalline thin fi lms. [ 18,[29][30][31][32][33][34][35] The local optoelectronic properties and changes in material composition have also been mapped using near-fi eld scanning optical microscopy (NSOM) probes as local sources of excitation. [36][37][38][39][40][41][42] Very recently, photoluminescence has emerged as a promising tool to map charge recombination [43][44][45] and carriers diffusion [ 46 ] with high spatial resolution. At low temperature (70 K), photoluminescence imaging with submicrometer resolution has been implemented to map a 10 meV quasi-Fermi level splitting in CIGS solar cells, where variations in the intensity signal were attributed to changes in the material composition. [ 47 ] Nevertheless, none of these imaging techniques provide a direct measurement of V oc within the material at operating conditions. A straightforward, universal, and accurate method to measure the V oc (and hence nonradiative recombination processes) with high spatial resolution in PV materials is still missing.Here, we present a new imaging technique based on illuminated KPFM to map the V oc of optoelectronic devices with nanoscale resolution <100 nm. We map the contact potential difference (CPD) of half or fully processed solar cells in the For most photovoltaic (PV) devices, the...
Complex interaction geometries offer a unique opportunity to modify the strength and sign of the Casimir force. However, measurements have traditionally been limited to sphere-plate or plate-plate configurations. Prior attempts to extend measurements to different geometries relied on either nanofabrication techniques that are limited to only a few materials or slight modifications of the sphere-plate geometry due to alignment difficulties of more intricate configurations. Here, we overcome this obstacle to present measurements of the Casimir force between two gold spheres using an atomic force microscope. Force measurements are alternated with topographical scans in the x-y plane to maintain alignment of the two spheres to within approximately 400 nm (∼1% of the sphere radii). Our experimental results are consistent with Lifshitz's theory using the proximity force approximation (PFA), and corrections to the PFA are bounded using nine sphere-sphere and three sphere-plate measurements with spheres of varying radii.
Kelvin probe force microscopy (KPFM) adapts an atomic force microscope to measure electric potential on surfaces at nanometer length scales. Here we demonstrate that Heterodyne-KPFM enables scan rates of several frames per minute in air, and concurrently maintains spatial resolution and voltage sensitivity comparable to frequency-modulation KPFM, the current spatial resolution standard. Two common classes of topography-coupled artifacts are shown to be avoidable with H-KPFM. A second implementation of H-KPFM is also introduced, in which the voltage signal is amplified by the first cantilever resonance for enhanced sensitivity. The enhanced temporal resolution of H-KPFM can enable the imaging of many dynamic processes, such as such as electrochromic switching, phase transitions, and device degredation (battery, solar, etc), which take place over seconds to minutes and involve changes in electric potential at nanometer lengths.
No abstract
Black phosphorus has attracted interest as a material for use in optoelectronic devices due to many favorable properties such as a high carrier mobility, field-effect, and a direct bandgap that can range from 0.3 eV in its bulk crystalline form to 2 eV for a single atomic layer. The low bandgap energy for bulk black phosphorus allows for direct transition photoabsorption that enables detection of light out to mid-infrared frequencies. In this work we characterize the room temperature optical response of a black phosphorus photoconductive detector at wavelengths ranging from 1.56 µm to 3.75 µm. Pulsed autocorrelation measurements in the near-infrared regime reveal a strong, sub-linear photocurrent nonlinearity with a response time of 1 ns, indicating that gigahertz electrical bandwidth is feasible. Time resolved photoconduction measurements covering near-and mid-infrared frequencies show a fast 65 ps rise time, followed by a carrier relaxation with a time scale that matches the intrinsic limit determined by autocorrelation. The sublinear photoresponse is shown to be caused by a reduction in the carrier relaxation time as more energy is absorbed in the black phosphorus flake and is well described by a carrier recombination model that is nonlinear with excess carrier density. The device exhibits a measured noise-equivalent power of 530 pW·Hz −1/2 which is the expected value for Johnson noise limited performance. The fast and sensitive room temperature photoresponse demonstrates that black phosphorus is a promising new material for mid-infrared optoelectronics.2
Light reflected off a material or absorbed within it exerts radiation pressure through the transfer of momentum. Micro/nano-mechanical transducers have become sensitive enough that radiation pressure can influence these systems. However, photothermal effects often accompany and overwhelm the radiation pressure, complicating its measurement. In this letter, we investigate the radiation force on an uncoated silicon nitride microcantilever in ambient conditions. We identify and separate the radiation pressure and photothermal forces through an analysis of the cantilever's frequency response. Further, by working in a regime where radiation pressure is dominant, we are able to accurately measure the radiation pressure. Experimental results are compared to theory and found to agree within the measured and calculated uncertainties. V C 2015 AIP Publishing LLC.
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