This paper presents a literature review concerning the characteristics of MgO (magnesium oxide or magnesia) and its application in cementitious materials. It starts with the characterization of MgO in terms of production processes, calcination temperatures, reactivity, and physical properties. Relationships between different MgO characteristics are established. Then, the influence of MgO incorporation on the properties of cementitious materials is investigated. The mechanical strength and durability behaviour of cement pastes, mortars and concrete mixes made with MgO are discussed. The studied properties of MgO–cement mixes include compressive strength, flexural strength, tensile strength, modulus of elasticity, water absorption, porosity, carbonation, chloride ion penetration, shrinkage, expansion, and hydration degree. In addition, microscopic analyses of MgO-cement mixes are also assessed. Summarizing the results of different studies, it is concluded that MgO incorporation in cementitious materials generally decreases the mechanical strength and shrinkage, and increases the porosity, expansion, carbonation and chloride ion migration. However, it should be emphasized that the properties of the specific MgO used (mainly the calcination temperature, the reactivity and the surface area) have a significant influence on the characteristics of the cementitious materials produced.

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This work analyzes the technical and economic viability of using coarse recycled aggregates from crushed concrete in shotcrete, as a primary lining support in tunnels. Four incorporation ratios of coarse natural aggregate (CNA) with coarse recycled concrete aggregates from concrete (CRCA) were studied: 0%, 20%, 50% and 100%. The mechanical properties of the dry-mix shotcrete were obtained in an independent experimental campaign. Initially, the technical viability of CRCA shotcrete was validated for deep rock tunnels, based on the convergence-confinement method. Two cases were studied to determine the equivalent thickness for each combination of replacement ratio using CRCA shotcrete: (i) similar stiffness and (ii) similar yield stress. Subsequently, an economic assessment was performed. The stiffness criterion increased the thickness below 10% in both the 20% and 50% replacement ratios, which shows their technical viability with very marginal cost increase (<5%). On the other hand, the maximum pressure criteria required higher increments, close to 30% in the 50% replacement ratio. A full replacement was proven to be impracticable in both analyses.

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