In the last quarter of 2021, there was a very significant eruption of the Cumbre Vieja volcano on the island of La Palma, belonging to the Canary Islands, Spain. It generated a large amount of pyroclastic volcanic materials, which must be studied for their possible applicability. This work studies the properties and applicability of the lava and volcanic ash generated in this process. The need for reconstruction of the areas of the island that suffered from this environmental catastrophe is considered in this study from the point of view of the valuation of the waste generated. For this purpose, the possibility of using the fine fraction of ashes and lava as a supplementary cement material (SCM) in the manufacture of cement is investigated. The volcanic material showed a chemical composition and atomic structure suitable for replacing clinker in the manufacture of Portland cement. In this study, the cementing and pozzolanic reaction characteristics of unprocessed volcanic materials and those processed by crushing procedures are analysed. To evaluate the cementitious potential by analysing the mechanical behaviour, a comparison with other types of mineral additions (fly ash, silica fume, and limestone filler) commonly used in cement manufacture or previously studied was carried out. The results of this study show that volcanic materials are feasible to be used in the manufacture of cement, with up to a 22% increase in pozzolanicity from 28 to 90 days, showing the high potential as a long-term supplementary cementitious material in cement manufacturing, though it is necessary to carry out crushing processes that improve their pozzolanic behaviour.
This work develops the manufacture of self-compacting concrete (SCC) with 50% cement reduction. As an alternative binder to cement, the viability of using an alkali-activated combination of stainless steel slag (SSS) and fly ash (FA) has been demonstrated. SSS was processed applying three different treatments. Binders were manufactured mixing 35% SSS with 65% FA, as precursors, and a hydroxide activating solution. This binder was replaced by the 50% cement for the manufacture of SCC. The results obtained show good mechanical properties and durability. The study shows a reduction in the use of cement in the manufacture of SCC reusing two wastes.
In recent years the use of biomass for electricity generation in thermal and cogeneration plants has increased worldwide because it is an environmentally clean fuel whose impact measured in greenhouse gas emissions is practically zero. However, biomass bottom ash, a waste produced during combustion, has also increased considerably, which has both a negative economic and environmental impact, due to landfill transport and management of this by-product. Although biomass bottom ash has potential characteristics for application in the manufacture of construction materials, its full-scale application is difficult because of the wide range in physicochemical properties, depending on the type of biomass burned, such as wood residue, olive waste, waste paper sludge, cocoa shell, etc., and the type of combustion process in the plant. This study reviews the influence on the physicochemical properties, mechanical behavior, and durability of different cement-based materials, such as mortars, concrete, and cement-treated granular material, manufactured from biomass bottom ash. The previous studies demonstrate the feasibility of substituting natural materials for biomass bottom ash in cement-based materials, presenting adequate mechanical behavior and durability properties to comply with the required technical specifications in different building materials.
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