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The Brazilian Tapajó s gold province contains the first evidence of high-sulfidation gold mineralization in the Amazonian Craton. The mineralization appears to be in large nested calderas. The Tapajó s-Parima (or Ventuari-Tapajó s) geological province consists of a metamorphic, igneous, and sedimentary sequence formed during a 2.10 to 1.87 Ga oceanÀcontinent orogeny. The high-sulfidation mineralization with magmatic-hydrothermal alunite is related to hydrothermal breccias hosted in a rhyolitic volcanic ring complex that contains granitic stocks ranging in age from 1.89 to 1.87 Ga. Cone-shaped hydrothermal breccias, which flare upward, contain vuggy silica and have an overlying brecciated cap of massive silica; the deposits are located in the uppermost part of a ring-structure volcanic cone. Drill cores of one of the hydrothermal breccias contain alunite, natroalunite, pyrophyllite, andalusite, quartz, rutile, diaspore, woodhouseite-svanbergite, kaolinite, and pyrite along with inclusions of enargite-luzonite, chalcopyrite, bornite, and covellite. The siliceous core of this alteration center is surrounded by advanced argillic and argillic alteration zones that grade outward into large areas of propylitically altered rocks with sericitic alteration assemblages at depth. Several occurrences and generations of alunite are observed. Alunite is disseminated in the advanced argillic haloes that envelop massive and vuggy silica or that underlie the brecciated silica cap. Coarse-grained alunite also occurs in branching veins and locally is partly replaced by a later generation of fine-grained alunite. Silicified hydrothermal breccias associated with the alunite contain an estimated reserve of 30 tonnes of gold in rock that grades up to 4.5 g t À1 Au. Seven alunite samples gave 40 Ar/ 39 Ar ages of 1.869 to 1.846 Ga, with various degrees of apparent minor Ar loss. Stable isotopic data require a magmatic-hydrothermal origin for the alunite, typical for high-sulfidation mineralization. The y 34 S values of most samples of alunite range from 14.0x to 36.9x. Sulfur isotopic alunite-pyrite and oxygen isotopic alunite SO 4 ÀOH temperatures range from 130 to 420 8C. The yD H 2 O and y 18 O H 2 O values for alunite-forming hydrothermal fluids suggest a

New 40 Ar/ 39 Ar analyses from a transect across the major tectonic units of the southwest Amazon craton document the heterogeneous effects of the late Mesoproterozoic collision with the Grenville margin of North America. Basement rocks of the Amazon and adjacent Paragua cratons mostly preserve pre-Grenvillian ages (older than 1.3 Ga). Localized isotopic age resetting at 1.18-1.12 Ga is caused by Grenvillian activation of widespread, sinistral strike-slip shear zones in the Amazon basement. In the Nova Brasilândia belt between these two cratons, new 40 Ar/ 39 Ar data record cooling through 920 Ma after the granulite facies deformation of this suture zone. Regional cooling rates calculated from compiled U/Pb, 40 Ar/ 39 Ar, and Rb/Sr thermochronologic data are used to establish post-Grenvillian exhumation patterns for the southwest Amazon and the North American belt. Paleodepths calculated for 1.0 Ga along a transect of the restored 1300-km-wide belt vary from uniformly deep levels (15-30 km) exposed in North America to shallower levels (5-15 km) observed in the southwest Amazon. We interpret this difference as reflective of a change in tectonic architecture, i.e., thrust-dominated deformation in Laurentia versus strike-slip dominated deformation in the Amazon, with a commensurate variation in crustal thickness. This interpretation explains the widespread preservation of both pre-Grenvillian ages and collisional ages from the Amazon craton, in contrast with the more homogeneous array of cooling ages from the North American Grenville Province marking the postorogenic extensional collapse of an overthickened crust. The asymmetrical orogenic architecture from the reconstructed Grenville belt mirrors cross sections proposed for modern orogenic belts where deep-crustal rocks are not yet exposed.

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The Río Negro-Juruena Province (RNJP) occupies a large portion of the western part of the Amazonian Craton and is a zone of complex granitization and migmatization. Regional metamorphism, in general, occurred in the upper amphibolite facies. The granites and gneisses of the RNJP yield Rb-Sr and Pb-Pb whole-rock isochron dates ranging from 1.8 Ga to 1.55 Ga, with initial 87 Sr/ 86 Sr ratios of ~ 0.703 and a single-stage model μ 1 value of ~ 8.

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