Phosphorus (P) is an essential and limited resource. Municipal wastewater is a promising source of P via reuse and could be used to replace P derived from phosphate rocks. The agricultural use of sewage sludge is restricted by legislation or is not practiced in several European countries due to environmental risks posed by organic micropollutants and pathogens. Several technologies have been developed in recent years to recover wastewater P. However, these technologies target different P-containing flows in wastewater treatment plants (effluent, digester supernatant, sewage sludge, and sewage sludge ash), use diverse engineering approaches and differ greatly with respect to P recycling rate, potential of removing or destroying pollutants, product quality, environmental impact and cost. This work compares 19 relevant P recovery technologies by considering their relationships with existing wastewater and sludge treatment systems. A combination of different methods, such as material flow analysis, damage units, reference soil method, annuity method, integrated cost calculation and a literature study on solubility, fertilizing effects and handling of recovered materials, is used to evaluate the different technologies with respect to technical, ecological and economic aspects. With regard to the manifold origins of data an uncertainty concept considering validity of data sources is applied. This analysis revealed that recovery from flows with dissolved P produces clean and plant-available materials. These techniques may even be beneficial from economic and technical perspectives under specific circumstances. However, the recovery rates (a maximum of 25%) relative to the wastewater treatment plant influent are relatively low. The approaches that recover P from sewage sludge apply complex technologies and generally achieve effective removal of heavy metals at moderate recovery rates (~40-50% relative to the WWTP input) and comparatively high costs. Sewage sludge ash is the most promising P source, with recovery rates of 60-90% relative to the wastewater P. The costs highly depend on the purity requirements of the recycled products but can be kept comparatively low, especially if synergies with existing industrial processes are exploited.
In this report, tests on the impact of the sludge properties on the oxygen transfer at low and high solids contents are presented. Additional to the oxygen transfer tests, the activated sludge was intensively analysed to examine the changes of the alpha-factor in relation to the sludge properties (rheology, EPS, CST, etc.). The alpha-factor did strongly decrease in all sludge types at increasing MLSS or increasing viscosity, respectively. In the second test stage, the impact of the aeration system was examined in detail. For these tests, the same sludge from a membrane bioreactor was used throughout. Apart from the impact of the power density in the reactor and the specific air throughput, the main focus was on the economic efficiency of the examined systems in cases of high MLSS. It became apparent that up to solids contents of 18 g/l the fine-bubble aeration is the most economically efficient method.
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