This paper presents a model of late‐glacial and post‐glacial deposition for the late‐Neogene sedimentary succession of the Archipelago Sea in the northern Baltic Sea. Four genetically related facies associations are described: (i) an ice‐proximal, acoustically stratified draped unit of glaciolacustrine rhythmites; (ii) an onlapping basin‐fill unit of rotated rhythmite clasts in an acoustically transparent to chaotic matrix interpreted as debris‐flow deposits; (iii) an ice‐distal, acoustically stratified to transparent, draped unit of post‐glacial lacustrine, weakly laminated to homogeneous deposits; and (iv) an acoustically stratified to transparent unit of brackish‐water, organic‐rich sediment drifts. The debris‐flow deposits of the unit 2 pass laterally into slide scars that truncate the unit 1; they are interpreted to result from a time interval of intense seismic activity due to bedrock stress release shortly after deglaciation of the area. Ice‐berg scouring and gravitational failure of oversteepened depositional slopes may also have contributed to the debris‐flow deposition. Comparisons to other late‐Neogene glaciated basins, such as the Hudson Bay or glacial lakes formed along the Laurentide ice sheet, suggest that the Archipelago Sea succession may record development typical for the deglaciation phase of large, low relief, epicontinental basins. The Carboniferous–Permian glacigenic Dwyka Formation in South Africa may provide an ancient analogue for the studied succession. Chronological control for the studied sediments is provided by the independent palaeomagnetic and AMS‐14C dating methods. In order to facilitate dating of the organic‐poor early post‐glacial deposits of the northern Baltic Sea, the 10 000 year long Lake Nautajärvi palaeomagnetic reference chronology (Ojala & Saarinen, 2002) is extended by 1200 years.
Abstract. Iron (Fe) plays a key role in sedimentary diagenetic processes in coastal systems, participating in various redox reactions and influencing the burial of organic carbon. Large amounts of Fe enter the marine environment from boreal river catchments associated with dissolved organic matter (DOM) and as colloidal Fe oxyhydroxides, principally ferrihydrite. However, the fate of this Fe pool in estuarine sediments has not been extensively studied. Here we show that flocculation processes along a salinity gradient in an estuary of the northern Baltic Sea efficiently transfer Fe and OM from the dissolved phase into particulate material that accumulates in the sediments. Flocculation of Fe and OM is partially decoupled. This is likely due to the presence of discrete colloidal ferrihydrite in the freshwater Fe pool, which responds differently from DOM to estuarine mixing. Further decoupling of Fe from OM occurs during sedimentation. While we observe a clear decline with distance offshore in the proportion of terrestrial material in the sedimentary particulate organic matter (POM) pool, the distribution of flocculated Fe in sediments is modulated by focusing effects. Labile Fe phases are most abundant at a deep site in the inner basin of the estuary, consistent with input from flocculation and subsequent focusing. The majority of the labile Fe pool is present as Fe (II), including both acid-volatile sulfur (AVS)-bound Fe and unsulfidized phases. The ubiquitous presence of unsulfidized Fe (II) throughout the sediment column suggests Fe (II)-OM complexes derived from reduction of flocculated Fe (III)-OM, while other Fe (II) phases are likely derived from the reduction of flocculated ferrihydrite. Depth-integrated rates of Fe (II) accumulation (AVS-Fe + unsulfidized Fe (II) + pyrite) for the period 1970–2015 are greater in the inner basin of the estuary with respect to a site further offshore, confirming higher rates of Fe reduction in near-shore areas. Mössbauer 57Fe spectroscopy shows that refractory Fe is composed largely of superparamagnetic Fe (III), high-spin Fe (II) in silicates, and, at one station, also oxide minerals derived from past industrial activities. Our results highlight that the cycling of Fe in boreal estuarine environments is complex, and that the partial decoupling of Fe from OM during flocculation and sedimentation is key to understanding the role of Fe in sedimentary diagenetic processes in coastal areas.
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