The development of real-time and sensitive humidity sensors is in great demand from smart home automation and modern public health. We hereby proposed an ultrafast and full-color colorimetric humidity sensor that consists of chitosan hydrogel sandwiched by a disordered metal nanoparticle layer and reflecting substrate. This hydrogel-based resonator changes its resonant frequency to external humidity conditions because the chitosan hydrogels are swollen under wet state and contracted under dry state. The response time of the sensor is ~10 4 faster than that of the conventional Fabry-Pérot design. The origins of fast gas permeation are membrane pores created by gaps between the metal nanoparticles. Such instantaneous and tunable response of a new hydrogel resonator is then exploited for colorimetric sensors, anti-counterfeiting applications, and high-resolution displays.
Covert polarization displays provide a barrier to the inadvertent viewing of stored optical information. For security and anti‐counterfeiting purposes, access to concealed information without compromising packaging aesthetics is required in certain situations. However, optical conversion with polarized light typically requires sophisticated nanostructures only possible with limited materials, which are not appropriate for application to objects requiring flexibility or conformability, and color selectivity. A flexible, large‐area covert polarization display based on ultrathin lossy nanocolumns with wide color selectivity is presented. Self‐aligned porous nanocolumns (PNCs) fabricated by glancing angle deposition are a facile approach to polarization distinguishable structures. PNCs deposited on metal are designed to switch color in accordance with polarization by ultrathin resonance, which is modeled using the complex effective refractive index. Several combinations of material and thickness are presented to extend color selectivity with the standard red green blue gamut and color palette. As a demonstration, covert polarization display labels are attached to daily objects with curved and wrinkled surfaces, and hidden quick response codes are revealed by polarization adjustment in indoor and outdoor environments. Moreover, a multifunctional water contact detection covert polarization display is demonstrated based on the sensitivity of PNCs to the refractive index of the analyte.
Nano-structural optical filters embedded in elastomers having high mechanical tunability provide the geometric degree of freedom for selective light manipulation. The active control of spectral information in typical structural optical filters is highly limited due to the substrate rigidity. Herein, we present mechanochromic transmissive optical filters by employing flexible and stretchable polymer-embedded silicon nanostructures. Si-based nanowire arrays (Si-NWAs) have been introduced to exhibit parametric resonance characteristics by controlling the period and/or diameter. Furthermore, the spectral shift phenomenon by increased diffraction efficiency was observed after the application of a uniaxial tensile force, which depends on the period of Si-NWAs with a large index contrast between the silicon nanowire and elastomer. The strain-sensitive properties of tunable Si-NWAs filters induced by light diffraction were calculated by simulation based on wave optics. The spectral tunability and light filtering features were simply demonstrated by stretching the Si-NWAs’ optical filters. Our proposed structure provides potential opportunities for a wide variety of applications, including dynamic color display, visual strain sensor and anti-counterfeiting.
Acclimatable colors in response to environmental stimuli, which are naturally endowed with some living things, can provide an opportunity for humans to recognize hazardous substances without taking empirical risks. Despite efforts to create artificial responsive colors, realistic applications in everyday life require an immediate/distinct colorimetric realization with wide chromatic selectivity. A dynamically responsive virus (M‐13 phage)‐based changeable coloring strategy is presented with a highly lossy resonant promoter (HLRP). An ultrathin M‐13 phage layer for rapid response to external stimuli displays colorimetric behavior, even in its subtle swelling with strong resonances on HLRP, which is modeled using the complex effective refractive index. Optimal designs of HLRP for several material combinations allow selective chromatic responsivity from the corresponding wide color palette without modification of the dynamic responsive layer. As a practical demonstration, the spatially designed colorimetric indicator, which is insensitive/sensitive to external stimuli, provides an intuitive perception of environmental changes with hidden/revealed patterns. Furthermore, the proposed colorimetric sensor is tested by exposure to various volatile organic chemicals and endocrine disrupting chemicals for versatile detectability, and is fabricated in a wafer‐scale sample for large‐area scalability.
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