Simulating abundances of stable water isotopologues, i.e. molecules differing in their isotopic composition, within climate models allows for comparisons with proxy data and, thus, for testing hypotheses about past climate and validating climate models under varying climatic conditions. However, many models are run without explicitly simulating water isotopologues. We investigate the possibility to replace the explicit physics-based simulation of oxygen isotopic composition in precipitation using machine learning methods. These methods estimate isotopic composition at each time step for given fields of surface temperature and precipitation amount. We implement convolutional neural networks (CNNs) based on the successful UNet architecture and test whether a spherical network architecture outperforms the naive approach of treating Earth's latitude-longitude grid as a flat image. Conducting a case study on a last millennium run with the iHadCM3 climate model, we find that roughly 40% of the temporal variance in the isotopic composition is explained by the emulations on interannual and monthly timescale, with spatially varying emulation quality. A modified version of the standard UNet architecture for flat images yields results that are equally good as the predictions by the spherical CNN. We test generalization to last millennium runs of other climate models and find that while the tested deep learning methods yield the best results on iHadCM3 data, the performance drops when predicting on other models and is comparable to simple pixel-wise linear regression. An extended choice of predictor variables and improving the robustness of learned climate-oxygen isotope relationships should be explored in future work.
<p>Tracing the spatio-temporal distribution of water isotopologues (e.g., H<sub>2</sub><sup>16</sup>O, H<sub>2</sub><sup>18</sup>O,HD<sup>16</sup>O, D<sub>2</sub><sup>16</sup>O), in the atmosphere allows insights in to the hydrological cycle and surface-atmosphere interactions. Strong relationships between atmospheric circulation and isotopologue variability exist, mitigated by fractionation during phase transitions of water. Isotopic gradients correlate with precipitation amount, temperature, with distance to source areas of evaporation and often follow topographic features. Isotope-enabled general circulation models (iGCMs) have been established to explicitly simulate the processes that lead to these distributions, in response to the changes in radiative forcing, boundary conditions, and including effects of internal variability of the climate system. However, few of these iGCMs<sup>1,2 </sup>of varying complexity exist to date and isotopic tracers decrease their computational efficiency.</p><p>Here, we evaluate the potential of replacing the explicit simulation of the isotopic component in the water cycle by statistical learning for offline model evaluation at interannual to multi-millennial timescales. This is challenging. While the relevant fractionation processes are well understood, the climate system is a chaotic, nonstationary system of high dimensionality. Therefore, successful statistical prediction requires the (so far elusive) understanding of the timescale-dependent relationships in the climate system. We present a case study on the feasibility of this approach.</p><p>We focus on the impact of variable selection (primarily surface temperature, precipitation and sea-level pressure) and boundary conditions (CO<sub>2 </sub>concentrations, ice sheet distribution). We also compare different approaches to dimensionality reduction, and compare the performance of different machine-learning approaches including simple linear regression, random forests, Gaussian Processes and different types of neural networks. The accuracy of the predictions is evaluated using regional and global area-weighted mean squared errors across training and evaluation data from individual GCM simulations and across climatic states.&#160;We find a high spatial variability of prediction accuracy, modest in many locations with the presently employed approaches. We obtain encouraging results for the prediction of isotope variability in Greenland and the Antarctic.</p><p>References</p><p>[1] Tindall, J. C., P. J. Valdes, and Louise C. Sime. "Stable water isotopes in HadCM3: Isotopic signature of El Ni&#241;o&#8211;Southern Oscillation and the tropical amount effect." <em>Journal of Geophysical Research: Atmospheres</em> 114.D4 (2009)</p><p>[2] Werner, Martin, et al. "Glacial&#8211;interglacial changes in H 2 18 O, HDO and deuterium excess&#8211;results from the fully coupled ECHAM5/MPI-OM Earth system model." <em>Geoscientific Model Development</em> 9.2 (2016): 647-670.</p>
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