Trisubstituted vinyl ethers were accessed via Chan–Evans–Lam coupling of vinyl trifluoroborates and primary aliphatic alcohols. This approach complements prior methods that required the use of neat liquid alcohol coupling partners....
The first extended pinacol reaction across an sp3–sp3 bond has been exploited to open a 1,3-bishomocubane cage in pursuit of conformationally restricted molecules for biological screening.
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