The maser-the microwave progenitor of the optical laser-has been confined to relative obscurity owing to its reliance on cryogenic refrigeration and high-vacuum systems. Despite this, it has found application in deep-space communications and radio astronomy owing to its unparalleled performance as a low-noise amplifier and oscillator. The recent demonstration of a room-temperature solid-state maser that utilizes polarized electron populations within the triplet states of photo-excited pentacene molecules in a p-terphenyl host paves the way for a new class of maser. However, p-terphenyl has poor thermal and mechanical properties, and the decay rates of the triplet sublevel of pentacene mean that only pulsed maser operation has been observed in this system. Alternative materials are therefore required to achieve continuous emission: inorganic materials that contain spin defects, such as diamond and silicon carbide, have been proposed. Here we report a continuous-wave room-temperature maser oscillator using optically pumped nitrogen-vacancy defect centres in diamond. This demonstration highlights the potential of room-temperature solid-state masers for use in a new generation of microwave devices that could find application in medicine, security, sensing and quantum technologies.
This paper details the investigation of the quality factor (Q), dielectric permittivity (e r ) and temperature coefficient of resonant frequency (s f ) of the TE 01d mode of the columbite binary niobate ceramics, with the formula MNb 2 O 6 where M 5 21 cation, in relation to their degree of sintering, microstructure and phase composition. The ceramics were made from a mixed oxide preparative route and fired over a range of temperatures from 8001 to 14001C, and most formed the columbite structure. A comprehensive study was made of the niobates containing the transition metal cations M 5 Mn 21 , Co 21 , Ni 21 , Cu 21 , and Zn 21 , and the group II metal cations M 5 Mg 21 , Ca 21 , Sr 21 , and Ba 21 . All columbite niobates were found to have e r between 17 and 22 and negative s f values between -45 and -76 ppm/1C, and ZnNb 2 O 6 , MgNb 2 O 6 , CaNb 2 O 6 , and CoNb 2 O 6 had high Qf values of 84 500, 79 600, 49 600, and 41 700 GHz, respectively. The Qf of MgNb 2 O 6 was found to rise to over 95 000 GHz when heated at 13001C for 50 h.
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Recently, the world’s first room-temperature maser was demonstrated. The maser consisted of a sapphire ring housing a crystal of pentacene-doped p-terphenyl, pumped by a pulsed rhodamine-dye laser. Stimulated emission of microwaves was aided by the high quality factor and small magnetic mode volume of the maser cavity yet the peak optical pumping power was 1.4 kW. Here we report dramatic miniaturization and 2 orders of magnitude reduction in optical pumping power for a room-temperature maser by coupling a strontium titanate resonator with the spin-polarized population inversion provided by triplet states in an optically excited pentacene-doped p-terphenyl crystal. We observe maser emission in a thimble-sized resonator using a xenon flash lamp as an optical pump source with peak optical power of 70 W. This is a significant step towards the goal of continuous maser operation.
Abstract-The complex permittivity and resistivity of float-zone high-resistivity silicon were measured at microwave frequencies for temperatures from 10 up to 400 K employing dielectric-resonator and composite dielectric-resonator techniques. At temperatures below 25 K, where all free carriers are frozen out, loss-tangent values of the order of 2 10 4 were measured, suggesting the existence of hopping conductivity or surface charge carrier conductivity in this temperature range. Use of a composite dielectricresonator technique enabled the measurement of materials having higher dielectric losses (or lower resistivities) with respect to the dielectric-resonator technique. The real part of permittivity of silicon proved to be frequency independent. Dielectric losses of high-resistivity silicon at microwave frequencies are mainly associated with conductivity and their behavior versus temperature can be satisfactory described by dc conductivity models, except at very low temperatures.
Reducing loss in microwave dielectrics is critical to improving performance in wireless communications systems. Grain boundaries in polycrystalline microwave dielectric ceramics have long been suspected of increasing dielectric loss. They are often cited as the main contributor to the observed difference in dielectric losses between single crystals and polycrystalline ceramics. The exact configuration of grain boundaries is problematic to quantify in practice and their influence on the dielectric loss difficult to distinguish from other defects such as porosity, oxygen vacancies, impurities, and dislocations. Here we measure the sensitivity of a single grain boundary in a magnesium oxide bi‐crystal to the polarization of an applied microwave field as a function of temperature.
The Rectenna (RECTifying antENNA), which was first demonstrated by William C. Brown in 1964 as a receiver for microwave power transmission, is now increasingly researched as a means of harvesting solar radiation. Tapping into the growing photovoltaic market, the attraction of the rectenna concept is the potential for devices that, in theory, are not limited in efficiency by the Shockley-Queisser limit. In this review, the history and operation of this 40-year old device concept is explored in the context of power transmission and the ever increasing interest in its potential applications at THz frequencies, through the infra-red and visible spectra. Recent modelling approaches that have predicted controversially high efficiency values at these frequencies are critically examined. It is proposed that to unlock any of the promised potential in the solar rectenna concept, there is a need for each constituent part to be improved beyond the current best performance, with the existing nanometer scale antennas, the rectification and the impedance matching solutions all falling short of the necessary efficiencies at THz frequencies. Advances in the fabrication, characterisation and understanding of the antenna and the rectifier are reviewed, and common solar rectenna design approaches are summarised. Finally, the socio-economic impact of success in this field is discussed and future work is proposed.
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