The
rapid growth of intermittent renewable energy (e.g., wind and
solar) demands low-cost and large-scale energy storage systems for
smooth and reliable power output, where redox-flow batteries (RFBs)
could find their niche. In this work, we introduce the first all-soluble
all-iron RFB based on iron as the same redox-active element but with
different coordination chemistries in alkaline aqueous system. The
adoption of the same redox-active element largely alleviates the challenging
problem of cross-contamination of metal ions in RFBs that use two
redox-active elements. An all-soluble all-iron RFB is constructed
by combining an iron–triethanolamine redox pair (i.e., [Fe(TEOA)OH]−/[Fe(TEOA)(OH)]2–) and an iron–cyanide
redox pair (i.e., Fe(CN)6
3–/Fe(CN)6
4–), creating 1.34 V of formal cell voltage.
Good performance and stability have been demonstrated, after addressing
some challenges, including the crossover of the ligand agent. As exemplified
by the all-soluble all-iron flow battery, combining redox pairs of
the same redox-active element with different coordination chemistries
could extend the spectrum of RFBs.
A zinc–iron redox-flow battery is developed that uses low cost redox materials and delivers high cell performance, consequently achieving an unprecedentedly low system capital cost under $100 per kW h.
In this work, a Lattice-Boltzmann-Method (LBM) model for simulating hysteresis in a proton exchange membrane fuel cell (PEMFC) electrode is presented. One of the main challenges hindering study of the cathode catalyst layer (CCL) in PEMFCs is the lack of understanding of two-phase transport and how it affects electrochemical performance. Previously, the microstructure details needed to build an accurate mesoscale model to examine such phenomena have eluded researchers; however, with advances in tomography and focused-ion-beam scanning-electron-microscopy (FIB-SEM), reconstruction of the complex porous media has become possible. Using LBM with these representations, the difficult problem of catalyst layer capillary hysteresis can be examined. In two-phase capillary hysteresis, both the equilibrium saturation position as well as its absolute value depends on the wetting history. Based on the models, it is ascertained that at lower capillary numbers, the liquid begins to undergo capillary fingering—only above a capillary pressure of 5 MPa, a regime change into stable displacement is observed. As capillary fingering does not lead to uniform removal of liquid, the prediction is that because high capillary pressures are needed to change to the regime of stable displacement, wicking is not as effective as the primary means of water removal.
Proton-exchange membranes fuel-cells (PEMFC) electrochemical performance insights are predicated on a detailed understanding of species transport in the cathode catalyst layer (CCL). Traditionally, CCL microstructure considerations were approached through approximations with unresolved pore-scale features. Such simplifications cause the loss of predictability for improving the economic feasibility via lower Pt-loading or non-noble metal catalysts. With advances in visualization, microstructure resolved mesoscale models become possible. A judicious combination of lattice Boltzmann (LBM) and finite volume (FVM) is an appropriate strategy for direct numerical simulation (DNS) of the physicochemical fields that remain unresolved due to spatiotemporal limitations.
The ionomer, which is responsible for proton transport, oxygen accessibility to reaction sites, and binding the carbon support particles, plays a central role in dictating the catalyst layer performance. In this work, we study the effect of ionomer distribution owing to the corrosion induced degradation mode in the catalyst layer based on a combined mesoscale modeling and experimental image-based data. It is observed that the coverage of the ionomer over the platinum-carbon interface is heterogeneous at the pore-scale which in turn can critically affect the electrode-scale performance. Further, an investigation of the response of the pristine as well as degraded microstructures that have been exposed to carbon support corrosion has been demonstrated to highlight the kinetic-transport underpinnings on the catalyst layer performance decay.
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