Morphologic and stratigraphic evidence shows that a late-glacial ice cap existed on part of the Eastern Cordillera of Ecuador (Lat. 0° 20′ S) on ground with a mean elevation of 4200 m where none exists now. An outlet glacier from an ca. 800 km2ice cap terminated at 3850 m altitude in the Papallacta valley on the eastern side of the plateau. Radiocarbon dates show that moraines formed by this advance were ice-free by 13,20014C yr B.P. Tephras and the age of organic deposits at the plateau edge indicate ice-free conditions before 11,80014C yr B.P. This interval was followed by the expansion of an ca. 140 km2ice cap that discharged glaciers into adjacent valleys where terminal moraines were built at 3950 m altitude. AMS and conventional radiocarbon dates from macrofossils, peat, and gyttja above and below till of the readvance indicate that the ice cap formed between ca. 11,000 and 10,00014C yr B.P. and was thus coeval with the European Younger Dryas event. The ice cap developed in response to a surface temperature cooling of at least 3°C in the tropical Andes, a finding that is consistent with a coupled equatorial/high latitude North Atlantic climate system operating at the late-glacial/Holocene transition. These results are further evidence that Younger Dryas cooling may have been a global event.

The South Caspian Basin has accumulated a sedimentary succession ∼20 km thick. Roughly half of this was deposited in the last 5.5 Ma, mainly in the largely lower Pliocene, fluvio‐lacustrine Productive Series, which is also the principal hydrocarbon reservoir succession in the basin. Heavy mineral data identify different sediment sources for both Productive Series sandstones and modern river sands. Lesser Caucasus sediment was supplied by the Palaeo‐Kura into the western part of the South Caspian Basin. Productive Series strata in the north of the basin were supplied by the Palaeo‐Volga, and represent a mixture of sediment from the Greater Caucasus and Russian Platform/Urals. Greater Caucasus sand input to the Palaeo‐Volga increased at the start of deposition of the Pereriva Suite, which is an important reservoir subunit of the Productive Series. We interpret this provenance shift as indicating enhanced uplift and exhumation of the Greater Caucasus within the Pliocene, during regional re‐organization of the Arabia–Eurasia collision, although late Cenozoic climate changes may have played a role.

The scanning electrochemical microscope (SECM) is used to generate localized corrosion at passivating iron surfaces by using the tip to generate Cl-ions. Use of the SECM allows the rapid establishment of a locally aggressive chemical environment at a preselected site on the iron surface. The susceptibility for passive layer breakdown and corrosion initiation was examined as a function of the time between the start of the passive layer growth and the formation of Cl-ions. The breakdown of the passive layer was found to depend strongly on the passivation potential and the site of Cl-formation on the iron surface. In addition to generating Cl-ions, the SECM tip was simultaneously used to detect large iron ion concentration fluctuations as corrosion began. Current fluctuations at the tip were observed and ascribed to precursors to the passive layer breakdown.* Electrochemical Society Student Member.

Correlating continental red-bed successions in the sub-surface is a common problem for the hydrocarbon industry. These successions are typically barren of fauna and often monotonous, leading to non-diagnostic wire-line log signatures. A high-resolution, high precision study of detrital garnet chemistry within Triassic reservoir sandstones from the Beryl Field of the North Sea failed to subdivide the sequence satisfactorily. However, the whole-rock concentrations of immobile trace elements such as Zr, Nb and Cr can be shown to be controlled primarily by the abundances of the heavy minerals zircon, rutile and chrome-spinel, respectively. The chemistry of detrital rutile and chrome spinel varies widely within any one sample, implying that the whole-rock concentrations of Nb and Cr are also a function of the chemistry of these heavy minerals. Having calibrated a type well with a detailed mineralogical and geochemical study, it was possible to correlate between wells using whole-rock geochemical cross-plots.

In the 23-km-diameter Haughton impact structure, Canadian High Arctic, in sulfate-rich bedrock, widespread hydrothermal sulfi de mineralization occurred in breccias formed during the impact. The sulfi des exhibit extreme sulfur isotopic fractionation relative to the original sulfate, requiring microbial sulfate reduction by thermophiles throughout the crater. This evidence of widespread microbial activity demonstrates that colonization could occur within the lifetime of a moderately sized, impact-induced hydrothermal system. The pyrite was subsequently oxidized to jarosite, which may also have been microbially mediated. The successful detection of evidence for microbial life suggests that it would be a valuable technique to deploy in sulfate-rich impact terrain on Mars.on June 5, 2015 geology.gsapubs.org Downloaded from