The development of a novel reactive unsaturated interfacial modifier for filled (magnesium hydroxide, aluminium hydroxide and calcium carbonate) polyolefins is reviewed. Initial work explored maleimide functional candidate molecules including 1,3-phenylene dimaleimide (1,3-PDM) and a range of linear alkyl dimaleimides. Most of the dimaleimides were very effective interfacial modifiers in polypropylene and poly(ethylene-co-vinylacetate) (18% w/w vinylacetate) based composites. However, the dimaleimides caused the composites to have a distinct pink/brown colouration apart from when the maleimide groups were spaced by a C12 alkyl chain. The problem with colour and high effective dosage prompted a switch to unsaturated carboxylic acid based systems. The performance of a range of unsaturated carboxylic acids and the hexafunctional monomer trimethylolpropane triacrylate are reviewed, together with a novel oligomeric unsaturated carboxylic acid (OUCA) based system developed by the Noveon Division of Lubrizol Limited. The data obtained from this series of interfacial modifiers, and adsorption studies on 1,3-PDM and OUCA, afforded some insight into the competing factors (such as the strength of adsorption versus ability to form a polymerised interfacial layer and the ability to react with matrix chains) that significantly affect the coupling performance of interfacial modifiers.
The current study investigates the effect of foreign object damage (FOD) on the pre-existing compressive residual stress field associated with laser shock peening (LSP) and its evolution upon combined LCF/HCF cycling. FOD was introduced onto an aerofoil-shaped specimen that had been previously LSP treated through ballistic impacts at angles of 0° and 45° to the leading edge. It is shown that the FOD notch created by 45° impact was asymmetric in shape and smaller in depth compared to that created at 0° impact. Significant through thickness compression was introduced parallel to the leading edge as a result of the LSP process. The residual strain distribution was mapped around the FOD notch by synchrotron X-ray radiation. The results show predominantly compressive stresses ahead of the notch, being greater for the 0 compared to 45 impact. No significant stress relaxation was observed after a combined (1000 HCF cycles superimposed on 1 LCF cycle) cycle.
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