We use a regional-scale, three-dimensional atmospheric model to evaluate U.S. air quality effects that would result from replacing HFC-134a in automobile air conditioners in the U.S. with HFO-1234yf. Although HFO-1234yf produces tropospheric ozone, the incremental amount is small, averaging less than 0.01% of total ozone formed during the simulation. We show that this production of ozone could be compensated for by a modest improvement in air conditioner efficiency. Atmospheric decomposition of HFO-1234yf produces trifluoroacetic acid (TFA), which is subject to wet and dry deposition. Deposition and concentrations of TFA are spatially variable due to HFO-1234yf's short atmospheric lifetime, with more localized peaks and less global transport when compared to HFC-134a. Over the 2.5 month simulation, deposition of TFA in the continental U.S. from mobile air conditioners averages 0.24 kg km(-2), substantially higher than previous estimates from all sources of current hydrofluorocarbons. Automobile air conditioning HFO-1234yf emissions are predicted to produce concentrations of TFA in Eastern U.S. rainfall at least double the values currently observed from all sources, natural and man-made. Our model predicts peak concentrations in rainfall of 1264 ng L(-1), a level that is 80x lower than the lowest level considered safe for the most sensitive aquatic organisms.

Electrifying transportation can reduce or eliminate dependence on foreign fuels, emission of green house gases, and emission of pollutants. One challenge is finding a pathway for vehicles that gains wide market acceptance to achieve a meaningful benefit. This paper evaluates several approaches aimed at making plug-in electric vehicles (EV) and plug-in hybrid electric vehicles (PHEVs) cost-effective including opportunity charging, replacing the battery over the vehicle life, improving battery life, reducing battery cost, and providing electric power directly to the vehicle during a portion of its travel. Many combinations of PHEV electric range and battery power are included. For each case, the model accounts for battery cycle life and the national distribution of driving distances to size the battery optimally. Using the current estimates of battery life and cost, only the dynamically plugged-in pathway was cost-effective to the consumer. Significant improvements in battery life and battery cost also made PHEVs more cost-effective than today's hybrid electric vehicles (HEVs) and conventional internal combustion engine vehicles (CVs).

Passenger compartment climate control is one of the largest auxiliary loads on a vehicle. Like conventional vehicles, electric vehicles (EVs) require climate control to maintain occupant comfort and safety, but cabin heating and air conditioning have a negative impact on driving range for all-electric vehicles. Range reduction caused by climate control and other factors is a barrier to widespread adoption of EVs. Reducing the thermal loads on the climate control system will extend driving range, thereby reducing consumer range anxiety and increasing the market penetration of EVs. Researchers at the National Renewable Energy Laboratory have investigated strategies for vehicle climate control load reduction, with special attention toward EVs. Outdoor vehicle thermal testing was conducted on two 2012 Ford Focus Electric vehicles to evaluate thermal management strategies for warm weather, including solar load reduction and cabin pre-ventilation. An advanced thermal test manikin was used to assess a zonal approach to climate control. In addition, vehicle thermal analysis was used to support testing by exploring thermal load reduction strategies, evaluating occupant thermal comfort, and calculating EV range impacts. Through stationary cooling tests and vehicle simulations, a zonal cooling configuration demonstrated range improvement of 6%-15%, depending on the drive cycle. A combined cooling configuration that incorporated thermal load reduction and zonal cooling strategies showed up to 33% improvement in EV range.

Current airconditioning systems can reduce the fuel economy of high fuel-economy vehicles by about 50% and reduce the fuel economy of today's mid-sized vehicles by more than 20% while increasing NOx by nearly 80% and CO by 70%. Automotive glazing has a significant impact on the peak and steady-state cooling loads of the vehicle. Glazing that reflects the infrared portion of the solar spectrum can reduce interior temperatures by 9°C and reject more than 500 W while the vehicle is parked. Such a windshield can improve the fuel economy of a compact car by about 0.3 km/L (0.7 mpg) over the SC03 drive cycle if the airconditioning system is appropriately down-sized.

The National Renewable Energy Laboratory has developed a suite of thermal comfort tools to assist in the development of smaller and more efficient climate control systems in automobiles. These tools, which include a 126-segment sweating manikin, a finite element physiological model of the human body, and a psychological model based on human testing, are designed to predict human thermal comfort in transient, nonuniform thermal environments, such as automobiles. The manikin measures the heat loss from the human body in the vehicle environment and sends the heat flux from each segment to the physiological model. The physiological model predicts the body's response to the environment, determines 126-segment skin temperatures, sweat rate, and breathing rate, and transmits the data to the manikin. The psychological model uses temperature data from the physiological model to predict the local and global thermal comfort as a function of local skin and core temperatures and their rates of change. Results of initial integration testing show the thermal response of a manikin segment to transient environmental conditions.

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People who wear protective uniforms that inhibit evaporation of sweat can experience reduced productivity and even health risks when their bodies cannot cool themselves. This paper describes a new sweating manikin and a numerical model of the human thermoregulatory system that evaluates the thermal response of an individual to transient, non-uniform thermal environments. The physiological model of the human thermoregulatory system controls a thermal manikin, resulting in surface temperature distributions representative of the human body. For example, surface temperatures of the extremities are cooler than those of the torso and head. The manikin contains batteries, a water reservoir, and wireless communications and controls that enable it to operate as long as 2 hours without external connections. The manikin has 120 separately controlled heating and sweating zones that result in high resolution for surface temperature, heat flux, and sweating control. The physiological finite element model uses approximately 40,000 solid thermal and blood network elements to represent the human body. The manikin and physiological model demonstrate their value in evaluating the thermoregulatory response of a person in a protective uniform. They can also be used to evaluate the effectiveness of personal cooling systems.

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