Two anthracene ligands, each coordinated differently are contained in the first two structurally characterized bis(anthracene) complexes of a Group 4 metal. Crystal structure analyses of [Ti(η6‐C14H10)(η4‐C14H10)(η2‐dmpe)] (dmpe=1,2 ‐ bis ( dimethylphosphino ) ethane) and [Ti(η4‐C14H10)(η2‐C14H10)(η5‐C5Me5)]− (see picture) show that they have unusual and completely different structures in the solid state.
Je zwei unterschiedlich koordinierende Anthracenliganden enthalten die beiden ersten strukturell charakterisierten Bis(anthracen)komplexe eines Metalls der 4. Nebengruppe. Kristallstrukturanalysen brachten die ungewöhnlichen und völlig unterschiedlichen Strukturen von [Ti(η6‐C14H10)(η4‐C14H10)(η2‐dmpe)] (dmpe = 1,2‐Bis(dimethylphosphino)ethan) und [Ti(η4‐C14H10)(η2‐C14H10)(η5‐C5Me5)]− (siehe rechts) zutage.
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