Recently the authors have demonstrated that compensated or “midgap” intrinsic hydrogenated microcrystalline silicon (μc-Si:H), as deposited by the Very High Frequency Glow Discharge (VHF-GD) technique, can be used as active layer in p-i-n solar cells. Compared to amorphous silicon (a-Si:H), μc-Si:H was found to have a significantly lower energy bandgap of around 1 eV. The combination of both materials (two absorbers with different gap energies) leads to a “real” tandem cell structure, which was called the “micromorph” cell. Micromorph cells can make better use of the sun's spectrum in contrast to conventional double-stacked a-Si:H / a-Si:H tandems.The present study will show that the compensation technique (involving boron “microdoping”) used sofar for obtaining midgap μc-Si:H can be replaced by the application of a gas purifier. The use of this gas purifier has a beneficial influence on the transport properties of undoped intrinsic μc-Si:H. By this procedure, increased cell efficiencies in both, single microcrystalline silicon p-i-n as well as micromorph cells could be obtained. In the first case 7.7 % stable, and in the second case 13.1% initial efficiency could be achieved under AM1.5 conditions. Preliminary light-soaking experiments performed on the tandem cells indicate that microcrystalline silicon could contribute to an enhancement of the stable efficiency performance. Micromorph cell manufacturing is fully compatible to a-Si:H technology; however, its deposition rate is still too low. With further increase of the rate, a similar cost reduction potential like in a-Si:H technology can be extrapolated.

A novel kind of nanostructured optical fiber, displaying an extremely high and optically broadband optomechanical nonlinearity, is presented. It comprises two closely spaced ultrathin glass membranes (webs) suspended in air and attached to the inner walls of a glass fiber capillary. Light guided in this dual-web structure can exert attractive or repulsive pressure on the webs, causing them to be pushed together or pulled apart. The elastic deflection of the webs is, in turn, coupled to the electromagnetic field distribution and results in a change in the effective refractive index within the fiber. Employing a pump-probe technique in an interferometric setup, optomechanically induced refractive index changes more than 10^{4} times larger than the Kerr effect are detected. Theoretical estimates of the optomechanical nonlinearity agree well with the experimental results. The dual-web fiber combines the sensitivity of a microoptomechanical device with the versatility of an optical fiber and could trigger new developments in the fields of nonlinear optics, optical metrology, and sensing.

Background organic matter in the Rhine River significantly affected the behavior of trichloroethene (TCE) and 1,2,4‐trichlorobenzene (TCB) in granular activated carbon (GAC) columns. The GAC column adsorption capacity for TCE was found to be more than 50 percent less than that found in batch adsorption experiments. The capacity for TCE of GAC preloaded with organic matter was found to be very similar to that of a TCE‐spiked GAC column, suggesting that the preloading isotherm approach can be useful in predicting GAC column capacity. Because of long‐term reductions in adsorption capacity, the breakthrough of TCE in a full‐scale column is not well predicted by the direct scaleup approach. Complete removal of TCB, presumably by biodegradation, was found after 40 days of operation.

It is interesting to pose the question: How best to design an optomechanical device, with no electronics, optical cavity, or laser gain, that will self-oscillate when pumped in a single pass with only a few mW of single-frequency laser power? One might begin with a mechanically resonant and highly compliant system offering very high optomechanical gain. Such a system, when pumped by single-frequency light, might self-oscillate at its resonant frequency. It is well-known, however, that this will occur only if the group velocity dispersion of the light is high enough so that phonons causing pump-to-Stokes conversion are sufficiently dissimilar to those causing pump-to-anti-Stokes conversion. Recently it was reported that two light-guiding membranes 20 μm wide, ∼500 nm thick and spaced by ∼500 nm, suspended inside a glass fiber capillary, oscillated spontaneously at its mechanical resonant frequency (∼6 MHz) when pumped with only a few mW of single-frequency light. This was surprising, since perfect Raman gain suppression would be expected. In detailed measurements, using an interferometric side-probing technique capable of resolving nanoweb movements as small as 10 pm, we map out the vibrations along the fiber and show that stimulated intermodal scattering to a higher-order optical mode frustrates gain suppression, permitting the structure to self-oscillate. A detailed theoretical analysis confirms this picture. This novel mechanism makes possible the design of single-pass optomechanical oscillators that require only a few mW of optical power, no electronics nor any optical resonator. The design could also be implemented in silicon or any other suitable material.

Recent experiments in the field of strong optomechanical interactions have focused on either structures that are simultaneously optically and mechanically resonant, or photonic crystal fibers pumped by a laser intensity modulated at a mechanical resonant frequency of the glass core. Here, we report continuous-wave (CW) pumped self-oscillations of a fiber nanostructure that is only mechanically resonant. Since the mechanism has close similarities to stimulated Raman scattering by molecules, it has been named stimulated Raman-like scattering. The structure consists of two submicrometer thick glass membranes (nanowebs), spaced by a few hundred nanometers and supported inside a 12-cm-long capillary fiber. It is driven into oscillation by a CW pump laser at powers as low as a few milliwatts. As the pump power is increased above threshold, a comb of Stokes and anti-Stokes lines is generated, spaced by the oscillator frequency of similar to 6 MHz. An unprecedentedly high Raman-like gain of similar to 4 x 10(6) m(-1) W-1 is inferred after analysis of the experimental data. Resonant frequencies as high as a few hundred megahertz are possible through the use of thicker and less-wide webs, suggesting that the structure can find application in passive mode-locking of fiber lasers, optical frequency metrology, and spectroscopy. (C) 2014 Optical Society of Americ

Over the past years, ultrafast lasers with average powers in the 100 W range have become a mature technology, with a multitude of applications in science and technology. Nonlinear temporal compression of these lasers to few-or even single-cycle duration is often essential, yet still hard to achieve, in particular at high repetition rates. Here we report a two-stage system for compressing pulses from a 1030 nm ytterbium fiber laser to single-cycle durations with 5 μJ output pulse energy at 9.6 MHz repetition rate. In the first stage, the laser pulses are compressed from 340 to 25 fs by spectral broadening in a krypton-filled single-ring photonic crystal fiber (SR-PCF), subsequent phase compensation being achieved with chirped mirrors. In the second stage, the pulses are further compressed to singlecycle duration by soliton-effect self-compression in a neon-filled SR-PCF. We estimate a pulse duration of ~3.4 fs at the fiber output by numerically back-propagating the measured pulses. Finally, we directly measured a pulse duration of 3.8 fs (1.25 optical cycles) after compensating (using chirped mirrors) the dispersion introduced by the optical elements after the fiber, more than 50% of the total pulse energy being in the main peak. The system can produce compressed pulses with peak powers >0.6 GW and a total transmission exceeding 70%.

The freely-suspended glass membranes in a dual-nanoweb fiber, driven at resonance by intensity-modulated light, exhibit a giant optomechanical nonlinearity. We experimentally investigate the effect of squeezed-film damping by exploring the pressure dependence of resonant frequency and mechanical quality factor. As a consequence of the unusually narrow slot between the nanowebs (22 mu m by 550nm), the gas-spring effect causes a pressure-dependent frequency shift that is similar to 15 times greater than typically measured in micro-electro-mechanical devices. When evacuated, the dual-nanoweb fiber yields a quality factor of similar to 3 600 and a resonant optomechanical nonlinear coefficient that is similar to 60 000 times larger than the Kerr effect. (C) 2013 AIP Publishing LLC

Soliton dynamics can be used to temporally compress laser pulses to few fs durations in many different spectral regions. Here we study analytically, numerically and experimentally the scaling of soliton dynamics in noble gas-filled hollow-core fibers. We identify an optimal parameter region, taking account of higher-order dispersion, photoionization, self-focusing, and modulational instability. Although for single-shots the effects of photoionization can be reduced by using lighter noble gases, they become increasingly important as the repetition rate rises. For the same optical nonlinearity, the higher pressure and longer diffusion times of the lighter gases can considerably enhance the long-term effects of ionization, as a result of pulse-by-pulse buildup of refractive index changes. To illustrate the counter-intuitive nature of these predictions, we compressed 250 fs pulses at 1030 nm in an 80-cm-long hollow-core photonic crystal fiber (core radius 15 µm) to ∼5 fs duration in argon and neon, and found that, although neon performed better at a repetition rate of 1 MHz, stable compression in argon was still possible up to 10 MHz.