Light‐driven metallo‐organic catalysis: Intramolecular photoelectron transfer in the heterodinuclear complex 1 facilitates the photocatalytic production of hydrogen and the selective hydrogenation of tolane to give cis‐stilbene. All three well‐coordinated parts of the supramolecular system are essential: the (tbbpy)2Ru fragment as a photoactive unit, the redox‐active bridging ligand as an electron relay and storage site, and the palladium as a catalytically active center.

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Since the mid 1970's interest in the chemistry and applications of ruthenium polypyridyl complexes has increased steadily. In this perspective, the development of this area is tracked and discussed taking into account new scientific developments as well as novel applications. The interaction between basic and applied research is of particular importance and selected examples are highlighted.

Electron transport through semiconductor and metallic nanoscale structures, molecular monolayers, and single molecules connected to external electrodes display rectification, switch, and staircase functionality of potential importance in future miniaturization of electronic devices. Common to most reported systems is, however, ultrahigh vacuum and/or cryogenic working conditions. Here we introduce a single-molecule device concept based on a class of robust redox active transition metal (Os(II)/(III)) complexes inserted between the working electrode and tip in an electrochemical scanning tunneling microscope (in situ STM). This configuration resembles a single-molecule transistor, where the reference electrode corresponds to the gate electrode. It operates at room temperature in a condensed matter (here aqueous) environment. Amplification on-off ratios up to 50 are found when the redox level is brought into the energy window between the Fermi levels of the electrodes by the overpotential ("gate voltage"). The current-voltage characteristics for two Os(II)/(III) complexes have been characterized systematically and supported by theoretical frames based on molecular charge transport theory.