This paper deals with the study of the temporal and spatial evolution of the dust formation in a capacitively coupled standard GEC cell in Ar/C 2 H 2 and Ar/CH 4 mixtures. To initiate the particle growth in the Ar/CH 4 discharge, we have either to apply transiently high power to the discharge or to inject transiently a pulse of C 2 H 2 . In the Ar/C 2 H 2 discharge, however, the particles are formed spontaneously at constant low power. The experiments underline the importance of acetylenic compounds for the nucleation process, i.e. for the first step of particle growth. Due to the different initiation process, the further temporal evolution of the dust formation is significantly different for both kinds of discharges. The dust particles are detected by means of laser beam scattering and by measuring the extinction of the laser beam after passing the discharge. The response of the plasma to the formation of dust has been analysed by emission spectroscopy and mass spectroscopy. The 7th harmonic signal of the rf driving voltage is a useful indicator for the presence of dust particles and their growth.

The formation of dust particles in argon diluted C2H2 plasmas was studied by means of Fourier transform infrared absorption spectroscopy and mass spectroscopy. The detection limit for infrared absorption was significantly improved by the use of a multipass technique. Measuring the intensity of the Rayleigh/Mie scattering of the infrared signal we found a periodicity of dust formation/vanishing (period of about 35 min in our experimental conditions). The fast disappearance of the dust from the plasma region at the end of every period is the evidence of a narrow particle size distribution, as confirmed by secondary electron micrographs of the collected powder. Characteristic infrared absorption features have their origin in absorption within the dust particles. Besides the strong presence of aliphatic hydrocarbons characteristic for amorphous hydrocarbon films, a significant amount of aromatic structures was detected. Heavy positive ions measured by ion-mass spectroscopy originate from polyacetilenic (C2nH2) and aromatic compounds. Time resolved mass spectra gave insight into the plasma response to the dust formation.

Reactive plasmas are nowadays widely used for technological applications. The spontaneous formation and growth of dust is a phenomenon frequently observed in such plasmas. The formation of dust particles has been observed in a great variety of different discharge types and in different kind of gases or gas mixtures. Due to the large variety of different phenomena that can be observed in reactive complex plasmas this article will address some selected (general) problems and examples that are specific for the physics and chemistry of such systems. These examples concern the formation and growth of dust particles in reactive plasmas, the mechanisms responsible for that growth processes, the spatial distribution of the dust particles within the discharge, the response of the plasma to the formation and growth of dust particles and some technological aspects.

Carbonaceous compounds are a significant component of interstellar dust, and the composition and structure of such materials is therefore of key importance. We present 1.5-15 m spectra of a plasma-polymerized carbonaceous material produced in radio-frequency discharge under low pressure, using C 2 H 2 as a precursor component. The infrared spectra of the resulting spheroidal carbonaceous nanoparticles reveal a strong aliphatic band (3.4 m feature), weak OH and carbonyl bands, and traces of aromatic compounds, all characteristics identified with dust in the diffuse interstellar medium of our Galaxy. The plasma polymerization process described here provides a convenient way to make carbonaceous interstellar dust analogs under controlled conditions and to compare their characteristics with astronomical observations. Here we focus on a comparison with the IR spectra of interstellar dust. The IR spectrum of carbonaceous dust in the diffuse interstellar medium is characterized by a strong 3.4 m CÀH stretching band and weak 6.8 and 7.2 m CÀH bending bands, with little evidence for the presence of oxygen in the form of carbonyl (C = O) or hydroxide (OH) groups. The plasma polymerization products produced under oxygen-poor conditions compare well with the peak position and profiles of the observed IR spectrum of diffuse dust. In addition, we find that addition of nitrogen to the plasma results in bands at 6.15 m (C = N band) and at 3 m (NH band). We note that, with the addition of nitrogen, the 3.4 m hydrocarbon band diminishes greatly in strength as the NH band grows. This may have implications for the puzzling absence of the 3.4 m hydrocarbon bands in the IR spectra of dust in dense molecular clouds, given that the presence of nitrogen-related bands has been established in dense-cloud dust.

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