A thermodynamic screening of 31 pure component working fluids for organic Rankine cycles (ORC) is given using BACKONE equation of state. The fluids are alkanes, fluorinated alkanes, ethers and fluorinated ethers. The ORC cycles operate between 100 and 30 1C typical for geothermal power plants at pressures mostly limited to 20 bar, but in some cases supercritical pressures are also considered. Thermal efficiencies Z th are presented for cycles of different types. In case of subcritical pressure processes one has to distinguish (1) whether the shape of the saturated vapour line in the T,s-diagram is bell-shaped or overhanging, and (2) whether the vapour entering the turbine is saturated or superheated. Moreover, in case that the vapour leaving the turbine is superheated, an internal heat exchanger (IHE) may be used. The highest Z th -values are obtained for the high boiling substances with overhanging saturated vapour line in subcritical processes with an IHE, e.g., for n-butane Z th ¼ 0.130. On the other hand, a pinch analysis for the heat transfer from the heat carrier with maximum temperature of 120 1C to the working fluid shows that the largest amount of heat can be transferred to a supercritical fluid and the least to a high-boiling subcritical fluid. r
In this work we present new molecular dynamics simulation results for the liquid-vapor interface of the pure Lennard-Jones fluid. Our aims were further investigations on the simulation setup and the simulation parameters to obtain reliable data for the coexisting densities as well as for the surface tension. The influence of the cutoff distance to the interfacial properties is investigated and long-range corrections to both the dynamics and the surface tension are applied. It is found that the saturated liquid densities from the surface simulations agree with those from the NpTϩtest particle method within 1% for sufficiently large simulation boxes; the saturated vapor densities agree within 4%. In order to obtain reliable values for the surface tension, cutoff radii of at least 5 molecular diameters supplemented by a tail correction are required.
A new equation of state (EOS) is proposed for the Helmholtz energy F of the Lennard-Jones fluid which represents the thermodynamic properties over a wide range of temperatures and densities. The EOS is written in the form of a generalized van der Waals equation, F = FH + F^, where FH is a hard body contribution and F^ an attractive dispersion force contribution. The expression for F H is closely related to the hybrid Barker-Henderson pertubation theory. The construction of F^ is accomplished with the Setzmann-Wagner optimization procedure on the basis of virial coefficients and critically assessed computer simulation data. A comparison with the EOS of Johnson et al. shows improvement in the description of the vapor-liquid coexistence properties, the pvT data, and in peculiar, of the caloric properties. A comparison with the EOS of Kolafa and Nezbeda which appeared after the bulk of this work was finished shows still an improvement in the standard deviations of the pressure and internal energy by about 30%.
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