Pit lake waters are often contaminated by acid mine drainage (AMD) from weathering of pyritic materials exposed by mining operations, leading to low pH, and high solute and heavy metal concentrations. Few cost-effective engineering solutions exist for large-scale environmental remediation of AMD-contaminated pit lakes. However, various studies have demonstrated that biological remediation strategies for remediating AMD-contaminated waters, including microbially-mediated sulphate reduction, show promise at the laboratory-scale. The addition of acidic mine water to raw sewage and workshop wastewaters in an evaporation pond provided an opportunity for a field-scale experiment as essentially a reversal of suggested in-situ treatment of acidic pit lakes by addition of organic carbon. The hyper-eutrophic evaporation pond initially contained high concentrations of nutrients, a pH [ 8, high levels of sulphate (500 mg L -1 ), and had regular algal blooms. Soon after the addition of the AMD pit water, the evaporation pond pH fell to 2.4, and electrical conductivity (EC) and most metal concentrations were elevated by one to two orders of magnitude. Over the following 18 months, the pH of the pond increased and the EC and metal concentrations decreased. After only 18 months of addition of AMD, pond water quality had returned to a level similar to that before AMD addition. These observations suggest that addition of low-grade organic materials shows promise for remediation of acid mine waters at field scale and warrants experimental investigation.
Pit lakes (abandoned flooded mine pits) represent a potentially valuable water resource to mining companies, the environment and regional communities across arid inland Australia. However, the water is often of low pH with high dissolved metal concentrations.The addition of organic matter to the pit lakes to enhance microbial sulfate reduction is potentially a cost effective and sustainable remediation strategy for these acid waters. However, the cost and availability of sufficient quantities of suitable organic substrates is typically limiting in these remote regions. Nevertheless, small quantities of sewage and green waste (organic garden waste) are often available in these areas from the regional towns which support the mines. This paper reports on preliminary microcosm laboratory experiments in preparation for the treatment of an acid (pH 2.2) coal mine pit lake in semi-arid tropical, inland north Queensland, Australia with municipal treated sewage and green waste.A laboratory experiment using microcosms (acrylic tubes) containing acid pit lake water and sediment were treated as follows; controls (untreated), sewage, green waste and sewage and green waste. The pH increased to a maximum of 5.5 in 145 days in the green waste and sewage treatment, with notable decreases of iron, aluminium and toxic heavy metals. Our results indicated that the green waste was a key component in alkalinity production and heavy metal removal.
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