Of four different representative types of ferroin chromogens tested, 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine (PDT) proved to be the most effectively adsorbed on Amberlite XAD-2.Isotherms for the adsorption of PDT and its iron(II) chelate on the copolymer were measured and interpreted. Distribution coefficients and retention capacities of PDT coated XAD-2 for various transition metal ions were determined. Effects of pH, different anions, and flow rates on column operation were evaluated. Applications of PDT coated columns include purification of reagents, concentration of trace metal ions from dilute solutions, and group separation of metal Ions prior to analysis. The analysis of seawater and of various reagent grade chemicals for trace quantities of iron, cobalt, nickel, copper, and zinc ions is described.
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