A key legacy of the recently launched TESS mission will be to provide the astronomical community with many of the best transiting exoplanet targets for atmospheric characterization. However, time is of the essence to take full advantage of this opportunity. JWST, although delayed, will still complete its nominal five year mission on a timeline that motivates rapid identification, confirmation, and mass measurement of the top atmospheric characterization targets from TESS. Beyond JWST, future dedicated missions for atmospheric studies such as ARIEL require the discovery and confirmation of several hundred additional sub-Jovian size planets (R p < 10 R ⊕ ) orbiting bright stars, beyond those known today, to ensure a successful statistical census of exoplanet atmospheres. Ground-based ELTs will also contribute to surveying the atmospheres of the transiting planets discovered by TESS. Here we present a set of two straightforward analytic metrics, quantifying the expected signal-to-noise in transmission and thermal emission spectroscopy for a given planet, that will allow the top atmospheric characterization targets to be readily identified among the TESS planet candidates. Targets that meet our proposed threshold values for these metrics would be encouraged for rapid follow-up and confirmation via radial velocity mass measurements. Based on the catalog of simulated TESS detections by Sullivan et al. (2015), we determine appropriate cutoff values of the metrics, such that the TESS mission will ultimately yield a sample of ∼ 300 high-quality atmospheric characterization targets across a range of planet size bins, extending down to Earth-size, potentially habitable worlds.

Infrared radiation emitted from a planet contains information about the chemical composition and vertical temperature profile of its atmosphere. If upper layers are cooler than lower layers, molecular gases will produce absorption features in the planetary thermal spectrum. Conversely, if there is a stratosphere-where temperature increases with altitude-these molecular features will be observed in emission. It has been suggested that stratospheres could form in highly irradiated exoplanets, but the extent to which this occurs is unresolved both theoretically and observationally. A previous claim for the presence of a stratosphere remains open to question, owing to the challenges posed by the highly variable host star and the low spectral resolution of the measurements. Here we report a near-infrared thermal spectrum for the ultrahot gas giant WASP-121b, which has an equilibrium temperature of approximately 2,500 kelvin. Water is resolved in emission, providing a detection of an exoplanet stratosphere at 5σ confidence. These observations imply that a substantial fraction of incident stellar radiation is retained at high altitudes in the atmosphere, possibly by absorbing chemical species such as gaseous vanadium oxide and titanium oxide.

Detailed characterization of exoplanets has begun to yield measurements of their atmospheric properties that constrain the planets' origins and evolution. For example, past observations of the dayside emission spectrum of the hot Jupiter WASP-12b indicated that its atmosphere has a high carbon-tooxygen ratio (C/O > 1), suggesting it had a different formation pathway than is commonly assumed for giant planets. Here we report a precise near-infrared transmission spectrum for WASP-12b based on six transit observations with the Hubble Space Telescope/Wide Field Camera 3. We bin the data in 13 spectrophotometric light curves from 0.84 -1.67 µm and measure the transit depths to a median precision of 51 ppm. We retrieve the atmospheric properties using the transmission spectrum and find strong evidence for water absorption (7 σ confidence). This detection marks the first high-confidence, spectroscopic identification of a molecule in the atmosphere of WASP-12b. The retrieved 1 σ water volume mixing ratio is between 10 −5 − 10 −2 , which is consistent with C/O > 1 to within 2 σ. However, we also introduce a new retrieval parameterization that fits for C/O and metallicity under the assumption of chemical equilibrium. With this approach, we constrain C/O to 0.5 +0.2 −0.3 at 1 σ and rule out a carbon-rich atmosphere composition (C/O > 1) at > 3 σ confidence. Further observations and modeling of the planet's global thermal structure and dynamics would aid in resolving the tension between our inferred C/O and previous constraints. Our findings highlight the importance of obtaining high-precision data with multiple observing techniques in order to obtain robust constraints on the chemistry and physics of exoplanet atmospheres.

We present a consistent optimal estimation retrieval analysis of 10hot Jupiter exoplanets, each with transmission spectral data spanning the visible to near-infrared wavelength range. Using the NEMESIS radiative transfer and retrieval tool, we calculate a range of possible atmospheric states for WASP-6b, WASP-12b, WASP-17b, WASP19b, WASP-31b, WASP-39b, HD 189733b, HD 209458b, HAT-P-1b, and HAT-P-12b. We find that the spectra of all 10planets are consistent with the presence of some atmospheric aerosol; WASP-6b, WASP-12b, WASP-17b, WASP-19b, HD 189733b, and HAT-P-12b are all fit best by Rayleigh scattering aerosols, whereas WASP-31b, WASP-39b and HD 209458b are better represented by a gray cloud model. HAT-P-1b has solutions that fall into both categories. WASP-6b, HAT-P-12b, HD 189733b, and WASP-12b must have aerosol extending to low atmospheric pressures (below 0.1 mbar). In general, planets with equilibrium temperatures between 1300 and 1700 K are best represented by deeper, gray cloud layers, whereas cooler or hotter planets are better fit using high Rayleigh scattering aerosol. We find little evidence for the presence of molecular absorbers other than H 2 O. Retrieval methods can provide a consistent picture across a range of hot Jupiter atmospheres with existing data, and will be a powerful tool for the interpretation of James Webb Space Telescope observations.