Multi-color phosphor-in-glass (PiG) film has been considered as a promising color converter in high-quality laser lighting owing to its outstanding merits of phosphor versatility, tunable luminescence, and simple preparation. However, the opto-thermal properties of PiG film are severely affected by the photon reabsorption and backward scattering of phosphor structure and the heat conduction of substrate. Herein, a unique sandwich design of phosphor structure was introduced in the multi-color PiG film for high-quality laser lighting. By elaborately synthesizing the borosilicate glass with low glass transition temperature (Tg), similar expansion coefficient, and high refractive index (RI), the sandwiched PiGs were prepared by sintering (~600 °C) broadband green and red phosphor glass films on the double sides of sapphire. The green and red PiG films were tightly coated on the sapphire with no delamination and maintained higher luminescence intensity than raw phosphors at high temperatures. By simultaneously coupling photon reabsorption and backward scattering, the sandwiched green PiG film—sapphire—red PiG film (G—S—R PiG) yields a high-quality white light with a high luminous efficacy of 163 lm/W and an excellent color rendering index (CRI) of 85.4 under a laser power of 2.4 W, which are the best comprehensive results yet reported. Benefiting from the ingenious sandwich design with heat-conducting sapphire and thin PiG films, the G—S—R PiG displays low working temperatures (< 200 °C) under high-power laser excitation. This work reveals the role of sandwiched phosphor structure in photon loss and heat dissipation, which provides a new strategy to design PiG films for high-quality laser lighting.

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Huge heat energy is ultimately generated in the color converter as a result of the nonradiative recombination of high‐power laser excitation. Inspired by the thermoelectric conversion, a high‐performance phosphor‐in‐glass film (PIGF) coated on a thermoelectric generator (TEG) for nonradiative energy recycling in high‐brightness laser lighting is proposed. The heat‐resistance PIGF with high luminescence is tightly coated on the hot‐side ceramic of TEG, while yielding a bright white light and promoting the heat conduction between PIGF and TEG. At the PIGF thickness of 60 µm, the PIGF‐TEG enables a natural white light with a luminous flux of 464 lm, a luminous efficacy of 194 lm W−1, a correlated color temperature (CCT) of 6552 K, and an appropriate chromaticity coordinate of (0.3117, 0.3302) under a laser power of 2.39 W. Aside from the high‐brightness output white light with a luminous flux of 1045 lm, the laser‐driven PIGF‐TEG produces the output voltage and current of 0.46 V and 174 mA under a laser power of 5.61 W, respectively. Therefore, the proposed PIGF‐TEG provides a potential strategy for heat energy recycling in high‐power phosphor‐converted lighting.