Tin halide perovskite's potential as a photovoltaic absorber has not been fully realized to date, largely due to its instability in ambient air. Here, we demonstrate by both experiments and simulations that the air instability of blackphase cesium tin iodide perovskite (γ-CsSnI 3 ) could be greatly lessened by a controlled incorporation of bismuth (Bi) ions into the crystal lattice. Hall effect measurements on films of γ-CsSnI 3 suggest the unwanted formation of a tin vacancy and p-type selfdoping can be effectively suppressed by the Bi incorporation. Structural and optical results indicate that the Bi incorporation markedly enhances the air stability by impeding the direct conversion of γ-CsSnI 3 to zero-dimensional Cs 2 SnI 6 . By using a stochastic surface walking (SSW) method integrating neural network (NN) potential and density functional theory (DFT), it is revealed that the remarkable enhanced stability could be attributed to a combination of factors originating from lattice-contraction-induced strain, a suppressed tin vacancy, and an increased energy barrier for the transformation of γ-CsSnI 3 to Cs 2 SnI 6 . This study provides physical insights into the stabilization mechanism of tin perovskites by heterovalent B-site engineering, paving the way for realizing stable and efficient lead-free perovskite photovoltaics.
Exploring new materials and structures to construct synaptic devices represents a promising route to fundamentally approach novel forms of computing. Nanocrystals (NCs) of halide perovskites possess unique charge transport characteristics, i.e., ionic−electronic coupling, holding considerable promise for energy-efficient and reconfigurable artificial synapses. Herein, we report solution-processed thin-film memristors from all-inorganic CsPbBr 3 perovskite NCs, functioning as an electrically programmable analog memory with good stability. The devices are demonstrated to successfully emulate a number of essential synaptic functions with low power consumption, including reversible potentiation and depression, short-term plasticity (STP), paired-pulse facilitation (PPF), and long-term plasticity (LTP), such as spike-number-dependent plasticity (SNDP), spike-rate-dependent plasticity (SRDP), spike-timing-dependent plasticity (STDP), and spike-voltage-dependent plasticity (SVDP). It is proposed that a coupled capacitive and inductive phenomenon originating from charge trapping and ion migration in CsPbBr 3 NC films, controlled by the amplitude and timing of the programming pulses, defines the degree of synaptic plasticity. A transition emerges from the fast traprelated capacitive regime to a slow ionic inductive regime, which enables continuous change of the film resistance and the magnitude of the electronic current, analogous to the synaptic weight modulation in biological synapses.
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