Two tetranuclear lanthanide complexes with the formula [Dy4(HL)4(OAc)2(H2O)2]•(Et3NH)2 (1) and [Gd4(HL)4(OAc)2(H2O)2]•(Et3NH)2•(CH3OH)2 (2) (H4L = N, N'-bis(3-hydroxylsalicylidene)benzene-1,2-diamine) were structurally and magnetically characterized. Dynamic magnetic studies shown that complex 1 exhibits two...
The studies of lanthanide-based single-molecule magnets (SMMs) have captivated the attention of researchers due to their great potential application in quantum information processing, storage and spintronics etc. Recent years have...
Two novel wheel-like lanthanide nanoclusters with 42 nuclearity [Ln42L14(OH)28(OAc)84] (abbreviated as Ln42, 1-Gd; 2-Dy, HL=3-methoxysalicylaldehyde O-vanillin) were structurally and magnetically characterized. The Ln42 species were constructed by O-vanillin and lanthanide...
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