Optical force, coming from momentum exchange during light-matter interactions, has been widely utilized to manipulate microscopic objects, though mostly in vacuum or in liquids. By contrast, due to the light-induced thermal effect, photophoretic force provides an alternative and effective way to transport light-absorbing particles in ambient gases. However, in most cases these forces work independently. Here, by employing the synergy of optical force and photophoretic force, we propose and experimentally demonstrate a configuration which can drive a micron-size metallic plate moving back and forth on a tapered fiber with supercontinuum light in ambient air. Optical pulling and oscillation of the metallic plate are experimentally realized. The results might open exhilarating possibilities in applications of optical driving and energy conversion.

Achieving light-driven motions in nonliquid environments presents formidable challenges, because microsized objects experience strong dry adhesion and intend to be stuck to contact surfaces with great tenacity. Here, in air and vacuum, we show rotary locomotion of a micrometer-sized metal plate with ~30 nm thickness, revolving around a microfiber. This motor is powered by pulsed light guided into the fiber as a coordinated consequence of an optically excited Lamb wave on the plate and favorable configuration of plate-fiber geometry. The motor, actuated by designed light pulses, crawls stepwise with subnanometer locomotion resolution. Furthermore, we can control the rotation velocity and step resolution by varying the repetition rate and pulse power, respectively. A light-actuated micromirror scanning with 0.001° resolution is then demonstrated on the basis of this motor. It offers unprecedented application potential for integrated micro-opto-electromechanical systems, outer-space all-optical precision mechanics and controls, and laser scanning for miniature lidar systems.

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Microcapsulated red phosphorus (MRP), with a melamine-formaldehyde resin coating layer, was prepared by two-step coating processes. The physical and chemical properties of MRP were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) and other measurements. The flame retardant action and mechanism of MRP in the halogen-free flame retardant (HFFR) polyolefins (PO) blends have been studied using cone calorimeter, limiting oxygen index (LOI), thermogravimetric analysis (TGA) and dynamic FTIR spectroscopy. The results show that the MRP, which is coated with melamine-formaldehyde resin, has a higher ignition point, a considerably lower amount of phosphine evolution and of water absorption compared with red phosphorus (RP) itself. The data observed by cone calorimeter, LOI and TGA measurements from the PO/HFFR blends demonstrated that the MRP can decrease the heat release rate and effective heat of combustion, and increase the thermostability and LOI values of PO materials. The dynamic FTIR results revealed the flame-retardant mechanism that RP can promote the formation of charred layers with the P-O and P-C complexes in the condensed phase during burning of polymer materials.

Vanadium (V) is an emerging contaminant in groundwater that can adversely affect human health. Although bioremediation has been shown effective, little is known on autotrophic V(V) bioreduction in the context of oligotrophic characteristics of groundwater. In this study, we demonstrate that efficient V(V) bioreductions can be coupled with bio-oxidation of elemental sulfur (S(0)) or zerovalent iron (Fe(0)), and the V(V) removal efficiencies reached 97.5 ± 1.2% and 86.6 ± 2.5% within 120 h using S(0) and Fe(0), respectively. V(IV) is the main reduction product and precipitates naturally in near-neutral conditions. Microbial community, functional gene, and metabolites analyses reveal that synthetic metabolisms among autotrophs and heterotrophs played major roles in V(V) reduction using S(0) and Fe(0). These results demonstrate a new approach for V(V) contaminated groundwater remediation.

Chemically synthesized metal nanowires are promising building blocks for next-generation photonic integrated circuits, but technological implementation in monolithic integration will be severely hampered by the lack of controllable and precise manipulation approaches, due to the strong adhesion of nanowires to substrates in non-liquid environments. Here, we demonstrate this obstacle can be removed by our proposed earthworm-like peristaltic crawling motion mechanism, based on the synergistic expansion, friction, and contraction in plasmon-driven metal nanowires in non-liquid environments. The evanescently excited surface plasmon greatly enhances the heating effect in metal nanowires, thereby generating surface acoustic waves to drive the nanowires crawling along silica microfibres. Advantages include sub-nanometer positioning accuracy, low actuation power, and self-parallel parking. We further demonstrate on-chip manipulations including transporting, positioning, orientation, and sorting, with on-situ operation, high selectivity, and great versatility. Our work paves the way to realize full co-integration of various functionalized photonic components on single chips.

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Realizing optical manipulation of microscopic objects is crucial in the research fields of life science, condensed matter physics, and physical chemistry. In non-liquid environments, this task is commonly regarded as difficult due to strong adhesive surface force (~µN) attached to solid interfaces that makes tiny optical driven force (~pN) insignificant. Here, by recognizing the microscopic interaction mechanism between friction force—the parallel component of surface force on a contact surface—and thermoelastic waves induced by pulsed optical absorption, we establish a general principle enabling the actuation of micro-objects on dry frictional surfaces based on the opto-thermo-mechanical effects. Theoretically, we predict that nanosecond pulsed optical absorption with mW-scale peak power is sufficient to tame µN-scale friction force. Experimentally, we demonstrate the two-dimensional spiral motion of gold plates on micro-fibers driven by nanosecond laser pulses, and reveal the rules of motion control. Our results pave the way for the future development of micro-scale actuators in non-liquid environments.