The Atmosphere Radiation Measurements Program's Ancillary Facility (AAF/SMART‐COMMIT) was deployed to Zhangye (39.082°N, 100.276°E), which is located in a semidesert area of northwest China, during the period of late April to mid June in 2008. We selected 11 cases to retrieve dust aerosol optical depth (AOD), Angstrom exponent, size distribution, single‐scattering albedo (SSA) and asymmetry parameter (ASY) from multifilter rotating shadowband radiometer (MFRSR) measurements. These cases are dominated by large particles with Angstrom exponent values ranging from 0.34 to 0.93. The values of AOD at 0.67 μm range from 0.07 to 0.25. The mean SSA value increases with wavelength from 0.76 ± 0.02 at 0.415 μm to 0.86 ± 0.01 at 0.870 μm, while the mean ASY value decreases from 0.74 ± 0.04 to 0.70 ± 0.02. Before estimating dust aerosol direct radiative forcing, a radiative closure experiment was performed to verify that the retrieved aerosol optical properties and other input parameters to the radiative transfer model appropriately represent atmospheric conditions. The daytime‐averaged differences between model simulations and ground observations are −8.5, −2.9, and −2.1 W m−2 for the total, diffuse, and direct normal fluxes, respectively. The mean difference in the instantaneous reflected solar fluxes at the top of atmosphere (TOA) between the model and CERES observations is 8.0 W m−2. The solar aerosol direct radiative forcing (ARF), averaged over a 24 h period, at the surface is −22.4 ± 8.9 W m−2, while the TOA ARF is small and has an average value of only 0.52 ± 1.69 W m−2. The daily averaged surface aerosol radiative forcing efficiency at 0.5 μm is −95.1 ± 10.3 W m−2τ−1. Our results illustrate that the primary role of dust aerosol is to alter the distribution of solar radiation within the climate system rather than to reflect solar energy to space. We assess the satellite aerosol optical depth products from Mutiangle Imaging Spectroradiometer (MISR) and Moderate Resolution Imaging Spectroradiometer (MODIS) observations by comparing them with our ground‐based retrievals. Reasonable agreements with the ground‐based observations are found for the MISR product and MODIS Deep Blue product.

Abstract. Lanzhou, which is located in a steep alpine valley in western China, is one of the most polluted cities in China during the wintertime. In this study, an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS), a seven-wavelength aethalometer, and a scanning mobility particle sizer (SMPS) were deployed during 10 January to 4 February 2014 to study the mass concentrations, chemical processes, and sources of submicrometer particulate matter (PM1). The average PM1 concentration during this study was 57.3 µg m−3 (ranging from 2.1 to 229.7 µg m−3 for hourly averages), with organic aerosol (OA) accounting for 51.2 %, followed by nitrate (16.5 %), sulfate (12.5 %), ammonium (10.3 %), black carbon (BC, 6.4 %), and chloride (3.0 %). The mass concentration of PM1 during winter was more than twice the average value observed at the same site in summer 2012 (24.5 µg m−3), but the mass fraction of OA was similar in the two seasons. Nitrate contributed a significantly higher fraction to the PM1 mass in winter than summer (16.5 % vs. 10 %), largely due to more favored partitioning to the particle phase at low air temperature. The mass fractions of both OA and nitrate increased by  ∼  5 % (47 to 52 for OA and 13 to 18 % for nitrate) with the increase of the total PM1 mass loading, while the average sulfate fraction decreased by 6 % (17 to 11 %), indicating the importance of OA and nitrate for the heavy air pollution events in Lanzhou. The size distributions of OA, nitrate, sulfate, ammonium, and chloride all peaked at  ∼  500 nm, with OA being slightly broader, suggesting that aerosol particles were internally mixed during winter, likely due to frequently calm and stagnant air conditions during wintertime in Lanzhou (average wind speed: 0.82 m s−1).The average mass spectrum of OA showed a medium oxidation degree (average O ∕ C ratio of 0.28), which was lower than that during summer 2012 (O ∕ C  =  0.33). This is consistent with weaker photochemical processing during winter. Positive matrix factorization (PMF) with the multi-linear engine (ME-2) solver identified six OA sources, i.e., a hydrocarbon-like OA (HOA), a biomass burning OA (BBOA), a cooking-emitted OA (COA), a coal combustion OA (CCOA), and two oxygenated OA (OOA) factors. One of the OOAs was less oxidized (LO-OOA), and the other one more oxidized (MO-OOA). LO-OOA was the most abundant OA component (22.3 % of OA mass), followed by CCOA (22.0 %), COA (20.2 %), MO-OOA (14.9 %), BBOA (10.8 %), and HOA (9.8 %). The mass fraction of primary OA ( =  HOA + BBOA + COA + CCOA) increased during high PM pollution periods, indicating that local primary emissions were a main reason for the formation of air pollution events in Lanzhou during winter. Radiocarbon (14C) measurement was conducted on four PM2.5 filter samples from this study, which allowed for a quantitative source apportionment of organic carbon (OC). The non-fossil sources on average accounted for 55 ± 3 % of OC, which could be mainly from biomass burning and cooking activities, suggesting the importance of non-fossil sources for the PM pollution in Lanzhou. Together with the PMF results, we also found that a large fraction (66 ± 10 %) of the secondary OC was from non-fossil OC.

Dust particles from the Taklimakan Desert can be lofted vertically up to 10 km due to the unique topography and northeasterly winds associated with certain synoptic conditions. Then they can be transported horizontally to regions far downwind by westerlies. We combined data from the Multiangle Imaging Spectroradiometer (MISR) and the Cloud-Aerosol Lidar with Orthogonal Polarization to investigate the three-dimensional distribution of dust over the Taklimakan Desert and surrounding areas. During spring and summer, a dust belt with high aerosol optical depths (AOD) extends eastward from the Taklimakan Desert to the Loess Plateau along the Hexi Corridor and southward to the Tibetan Plateau. However, the dust extinction coefficients decrease rapidly from 0.340 km À1 near surface to 0.015 km À1 at 5 km in spring, while the extinction values vary within 0.100 ± 0.020 between the altitudes of 1.6 and 3.5 km and decrease to 0.023 km À1 at 5 km in summer, indicating that dust aerosol is relatively well mixed vertically. We further used MISR daily AOD to identify high-and low-dust days and then analyzed composite difference patterns of temperature, geopotential height, and wind between high-and low-dust days. It was found that although the synoptic situations of spring and summer are quite different, there are two common features: a strong anticyclonic wind anomaly over the Taklimakan at 500 hPa and an enhanced easterly wind over the Tarim Basin at 850 hPa for the two seasons. These conditions are favorable for dust entrainment from the dry desert surface, vertical lofting, and horizontal transport.

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